ＮＭＲ検出のためペリレンジイミド由来の薬剤を素にした新たなディスコティック液晶

用于核磁共振检测的基于苝二酰亚胺衍生药物的新型盘状液晶

• 批准号: 15F15773
• 负责人: HILL Jonathan
• 金额: $ 1.47万
• 依托单位: National Institute for Materials Science
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for JSPS Fellows
• 财政年份: 2015
• 资助国家: 日本
• 起止时间: 2015-11-09 至 2018-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-15F15773/
• 关键词: Perylene diimide; Chirality; Self-assembly; NMR Spectroscopy; NMR spectroscopy; perylene diimide; chirality

Synthesis and purification of several classes of chiral perylene diimide (highly colored pigments) including amionic and cationic compounds was completed. Physical properties of the compounds were investigated revealing their assembly into chiral structures in solutions and formation of cholesteric liquid crystals in aqueous solvent mixtures. The effects of solvent and concentration were investigated. The liquid crystal compounds were applied in NMR experiments for the determination of enantiomeric excess. Chiral self-assemblies of the materials were metallated forming chiral coordination complexes suitable for possible catalytic applications.Two manuscripts in preparation.

完成了几类手性二酰亚胺（包括高色色素）的合成和纯化，包括氨和阳离子化合物。研究了化合物的物理特性，以揭示其在水溶液混合物中溶液和胆汁脂液液晶体的形成中的手性结构中。研究了溶剂和浓度的影响。将液晶化合物应用于NMR实验中，以测定对映体过量。材料的手性自组件是金属形成的手性配位络合物，适合于可能的催化应用。

项目成果

Chiral Self-Assembly of Perylene Diimides

苝二酰亚胺的手性自组装

• 发表时间: 2017
• 作者: Geraldine Echue;Katsuhiko Ariga;Jonathan P. Hill
• 通讯作者: Jonathan P. Hill

Self-assembly of Perlyene Diimides

苝二酰亚胺的自组装

• 发表时间: 2017
• 作者: Geraldine Echue;Katsuhiko Ariga;Jonathan P. Hill
• 通讯作者: Jonathan P. Hill