Synthesis of expanded poly(α-amino acid)s having metal complex skeleton and construction of secondary structures

具有金属络合物骨架的膨胀聚(α-氨基酸)的合成及二级结构的构建

• 批准号: 20550063
• 负责人: OKAMURA Taka-aki
• 金额: $ 3.16万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2008
• 资助国家: 日本
• 起止时间: 2008 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20550063/
• 关键词: 超分子化学; 金属錯体; ペプチド; 非天然型アミノ酸; 超分子化; 金属錯体化学

A series of expanded poly(α-amino acid)s containing metal complexes was designed and synthesized. The molecular structures in solution and the crystal structures were determined. The conformation of the polymer depends finely on the component amino acids. Slight changes of the side chain of amino acid residues resulted in varieties of conformations, e.g., helical and zigzag structures. A suitable select of linkage could alter the handedness of the helix.

设计并合成了一系列含有金属配合物的膨胀聚(α-氨基酸)，并测定了聚合物的构象在很大程度上取决于氨基酸的组成。氨基酸残基链产生多种构象，例如螺旋和锯齿形结构，合适的连接选择可以改变螺旋的旋向性。

项目成果

Synthesis, structure and property of lanthanide-organic frameworks with pyridyl ; and carboxylate-containing ligand

吡啶基稀土有机骨架材料的合成、结构与性能；

• 发表时间: 2011
• 作者: Man

Reversible Single-Crystal-to-Single-Crystal Transformation and Highly Selective Adsorption Property of Three-Dimensional Cobalt(II) Frameworks

三维钴(II)骨架的可逆单晶-单晶转变及高选择性吸附性能

• 发表时间: 2011
• 作者: Zhi Su; Taka
• 通讯作者: Taka

Ligand-directed and pH-controlled assembly of chiral 3d-3d heterometallic metal-organic frameworks

手性 3d-3d 异金属金属有机框架的配体引导和 pH 控制组装

• 发表时间: 2010
• 作者: Z.Su; J.Fan; T.Okamura; W.
• 通讯作者: W.

Imidazolate-bridged dinuclear copper(II) complex with new macrocyclic ligand bearing two 1H-imidazol-4-yl-pendants

咪唑桥联双核铜 (II) 络合物，具有带有两个 1H-咪唑-4-基侧垂的新大环配体

• 发表时间: 2010
• 作者: Zhao

Zinc(II) Complexes with 1H-Imidazol-4-yl-Containing Polyamine Ligand

锌 (II) 与含 1H-咪唑-4-基的多胺配体的配合物

• 发表时间: 2010
• 作者: Zhao