Vaporization mechanism and ion-pair structure of protic ionic liquids

质子离子液体的汽化机理和离子对结构

• 批准号: 24750013
• 负责人: AKAI Nobuyuki
• 金额: $ 3万
• 依托单位: Tokyo University of Agriculture and Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2012
• 资助国家: 日本
• 起止时间: 2012-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-24750013/
• 关键词: イオン液体; 蒸発メカニズム; 赤外分光法; 量子化学計算; 蒸発機構; イオン対構造; イオニシティー; 赤外分光; プロトン性イオン液体

In order to understand the nature of room temperature ionic liquids which are expected to become nobel materials, vaporation machanism and structures of some room temperature ionic liquids were investigated by low-temperature matrix-isolation infrared spectroscopy as a experimantal method with aids of high level quantum chemical calculations. Especially, we focused on protic ionic liquids simply made by a mixing of one acid and one base. Although it had been usually considered that the parent acid and base are released in the gas phase from protic ionic liquid by proton transfer from anion to cation, another vaporization mechanism that anion-cation pair directly evaporates from the protic ionic liquid composed of strong acid and strong base were found in this study.

为了理解有望成为诺贝尔材料的室温离子液体的性质，通过低温基质 - 溶性红外光谱验证了一种室温离子液体的蒸发和某些室温离子液体的结构，作为一种实验方法，该方法具有高水平量子化学计算的帮助。 尤其是，我们专注于仅通过一种酸和一个碱的混合而制成的普通离子液体。 尽管通常认为由质子从阴离子到阳离子的质子转移从普罗尼克的离子液体中释放出父酸和碱，但在这项研究中发现了一种直接从由强酸和强碱的原始离子液中蒸发的一种蒸发机制。

项目成果

フェニルアゾ基を有するイオン液体のフォトクロミック反応

离子液体与苯基偶氮基团的光致变色反应

• 发表时间: 2012
• 作者: 吉田剛;河森大樹;浅香亨;赤井伸行;河合明雄;渋谷一彦
• 通讯作者: 渋谷一彦

イオン液体の固液界面近傍における励起状態ダイナミクス

离子液体固液界面附近的激发态动力学

• 发表时间: 2012
• 作者: 小倉隆宏;河森大樹;赤井伸行;河合明雄;渋谷一彦
• 通讯作者: 渋谷一彦

Solute Size-Dependent Rotational Diffusion of Nitroxide Radicals in Ionic Liquids as Studied by EPR Spectroscopy

EPR 光谱研究离子液体中氮氧自由基的溶质尺寸依赖性旋转扩散

• DOI: 10.1246/cl.130682
• 发表时间: 2013
• 期刊: Chem.Letters
• 作者: Yusuke Miyake;Nobuyuki Akai;Kazuhiko Shibuya;Akio Kawai
• 通讯作者: Akio Kawai