Chemical transformations promoted by carbon-based nanocavity materials

碳基纳米腔材料促进化学转化

• 批准号: 23550178
• 负责人: IWAMATSU Sho-ichi
• 金额: $ 3.33万
• 依托单位: Nagoya University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011 至 2013
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23550178/
• 关键词: 物質変換触媒; ナノカーボン; ホスト材料; 機能性触媒

This research aims to develop novel chemical transformations promoted by carbon-based nano cavity materials which are prepared by multiple cage scission -reactions of [60]fullerene. We have focused on (1) activations and chemical transformations of the trapped molecules inside nano cavities and (2) chemical transformations based on the unusual reactivity characteristic of nano cavity materials, especially around the opening moieties (orifices). In respect to the latter, oxidative dimerization reactions of benzylamines proceed in the presence of catalytic amount of a cavity material and the corresponding imines are obtained in good yields.

本研究旨在开发由[60]富勒烯的多重笼断裂反应制备的碳基纳米空腔材料促进的新型化学转化。我们重点关注（1）纳米腔内捕获分子的激活和化学转化，以及（2）基于纳米腔材料异常反应特性的化学转化，特别是在开放部分（孔口）周围。对于后者，苄胺的氧化二聚反应在催化量的空腔材料存在下进行，并以良好的收率获得相应的亚胺。

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