Synthesis and application of porous crosslinked polymers and carbons

多孔交联聚合物和碳的合成及应用

• 批准号: 22750203
• 负责人: KANAMORI Kazuyoshi
• 金额: $ 2.66万
• 依托单位: Kyoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2010
• 资助国家: 日本
• 起止时间: 2010 至 2011
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22750203/
• 关键词: 多孔体; 架橋高分子; ゲル; 炭素材料; 高分子合成; 高分子構造・物性; 付加・縮合; 多孔性高分子; 多孔性炭素; マクロ孔; メソ孔; ミクロ孔; 比表面積; 電気化学測定; 電気二重層キャパシタ

Monolithic activated carbon electrodes with high specific surface area have been prepared through carbonization and activation of poly(divinylbenzene), which were prepared by controlled/living radical polymerization. These electrodes show relatively high specific capacitance and good cycle and rate performances. In addition, carbonization of macroporous melamine-formaldehyde resins has been investigated for the purpose of obtaining nitrogen-doped porous carbons. By introducing resorcinol in the preparation of resins, it has been demonstrated that nitrogen-doped carbons with retained macroporous structure have been obtained.

通过受控/活性自由基聚合制备聚二乙烯基苯，通过碳化和活化制备了具有高比表面积的整体式活性炭电极。这些电极表现出相对较高的比电容以及良好的循环和倍率性能。此外，为了获得氮掺杂的多孔碳，还研究了大孔三聚氰胺甲醛树脂的碳化。通过在树脂制备中引入间苯二酚，已证明获得了保留大孔结构的氮掺杂碳。

项目成果

Facile Preparation of Monolithic LiFePO4/Carbon Composites with Well-Defined Macropores for a Lithium-Ion Battery

• DOI: 10.1021/cm2021438
• 发表时间: 2011-12-13
• 期刊: CHEMISTRY OF MATERIALS
• 影响因子: 8.6
• 作者: Hasegawa, George;Ishihara, Yuya;Abe, Takeshi
• 通讯作者: Abe, Takeshi

液相における重合反応に基づく新規モノリス状多孔体の開発

基于液相聚合反应的新型整体式多孔材料的开发

• 发表时间: 2012
• 作者: 前山洋輔;則末智久;宮田貴章;山崎慎一;金森主祥
• 通讯作者: 金森主祥

Macroporous carbon monoliths with high surface area for electric double-layer capacitor

用于双电层电容器的高比表面积大孔碳整料

• DOI: 10.1557/opl.2011.604
• 发表时间: 2011
• 期刊: Mater. Res. Soc. Symp. Proc
• 作者: George HASEGAWA;Mami AOKI;Kazuyoshi KANAMORI;Kazuki NAKANISHI;Teiichi HANADA;Kiyoharu TADANAGA
• 通讯作者: Kiyoharu TADANAGA

スチレン-ジビニルベンゼン共重合系におけるマクロ多孔性架橋高分子の合成と細孔解析

苯乙烯-二乙烯基苯共聚体系大孔交联聚合物的合成及孔分析

• 发表时间: 2010
• 作者: M.ARIVANANDHAN;R.GOTOH;T.WATAHIKI;K.FUJIWARA;Y.HAYAKAWA;M.KONAGAI;S.UDA;高橋祐介,秋本雅史,川本益揮,長瀬裕;田上尚敬
• 通讯作者: 田上尚敬

Monolithic electrode for electric double-layer capacitors based on macro/meso/microporous S-Containing activated carbon with high surface area

• DOI: 10.1039/c0jm03793a
• 发表时间: 2011-01-01
• 期刊: JOURNAL OF MATERIALS CHEMISTRY
• 作者: Hasegawa, George;Aoki, Mami;Tadanaga, Kiyoharu
• 通讯作者: Tadanaga, Kiyoharu