Preparation and Characterization of Novel Luminescent Transition-MetalComplexes Bearing Sulfanenitrile Ligand

含磺腈配体的新型发光过渡金属配合物的制备及表征

• 批准号: 22550045
• 负责人: FUJII Takayoshi
• 金额: $ 3.16万
• 依托单位: Nihon University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2010
• 资助国家: 日本
• 起止时间: 2010 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22550045/
• 关键词: 有機化学; 有機元素化学; 錯体化学; 光発光; 硫黄?窒素化学; 硫黄-窒素化学

(1) Syntheses and Photophysical Properties of noble Mixed Ligand Pt(II) Complexes: The heteroleptic complexes, [Pt(N^N)(1)]X_2 [N^N = 1,10-phenanthroline (phen) (2),4,7-diphenyl- phenanthroline (bathophen) (3); X = PF_6 (a) and ClO_4 (b)] and [Pt(C^N)(ndsdsd)]X [C^N= 2-phenylpyridine (ppy) (4) and benzo[h]quinoline (bzq) (5); X = PF_6 (a) and ClO_4 (b)] were prepared,and the molecular structures of 2?5 were characterized. Complexes 2 and 3a are very weaklyluminescent in solution, whereas they show highly emissive in the solid state (Φ_em = 0.11?0.27).(2) Syntheses and Photophysical Properties of Pd Complexes Containing a Disulfanenitrile Ligand: Thehomoleptic complex, [Pd(1)_2]Cl_2 (6) and the heteroleptic complexes, [Pd(diimine)(1)]Cl_2 (diimine:2,2’-bipyridine (7), 1,10-phenanthroline (8), and 4,7-diphenyl-1,10-phenanthroline (9)) were prepared,and the molecular structures of 6?9 were characterized. The complexes 7?8 are not emissive at ambient temperature in the solid state, but the homoleptic complex 6 shows an unstructured emission bond (λ_max = 690 nm).

(1) 高贵混合配体Pt(II)配合物的合成和光物理性质：杂配配合物[Pt(N^N)(1)]X_2 [N^N = 1,10-菲咯啉(phen) (2)， 4，7-二苯基菲咯啉（bathophen）（3）；X=PF_6（a）和ClO_4（b）]和[Pt(C^N)(ndsdsd)]X [C^N= 2-苯基吡啶 (ppy) (4) 和苯并[h]喹啉 (bzq) (5)；X = PF_6 (a) 和 ClO_4 (b)； ]制备了配合物2?5的分子结构，并表征了配合物2和3a在溶液中发光非常弱，而在溶液中则表现出高发射性。固态(Φ_em = 0.11?0.27)。(2) 含二硫腈配体的Pd配合物的合成和光物理性质：均配配合物[Pd(1)_2]Cl_2 (6) 和杂配配合物[Pd(二亚胺)( 1)]Cl_2(二亚胺:2,2'-联吡啶(7),制备了1,10-菲咯啉(8)和4,7-二苯基-1,10-菲咯啉(9))，并表征了配合物6?9的分子结构，配合物7?8在环境温度下不发光。在固态下，但同配配合物 6 显示出非结构化发射键（λ_max = 690 nm）。

项目成果

Syntheses, Crystal Structures, and Photophysical Properties of Platinum(II) Complexes Containing a Disulfanenitrile Ligand

含有二硫腈配体的铂(II)配合物的合成、晶体结构和光物理性质

• DOI: 10.1246/bcsj.20120336
• 发表时间: 2013
• 期刊: Bulletin of the Chemical Society of Japan
• 影响因子: 4
• 作者: Hiroya Honda;Takayoshi Fujii;Junpei Kuwabara;Takaki Kanbara;Hiroya Honda
• 通讯作者: Hiroya Honda

Syntheses and crystal structures of[Cu_3{μ-(NSPh2)N}_2Cl_2]and[Cu_3{μ-(NSPh_2)_2N}_2{(NSPh_2)_2N}_2]Cl_2

[Cu_3{μ-(NSPh2)N}_2Cl_2]和[Cu_3{μ-(NSPh_2)_2N}_2{(NSPh_2)_2N}_2]Cl_2的合成及晶体结构

• 发表时间: 2010
• 期刊: International Journal of Inorganic Chemistry
• 作者: Takayoshi Fujii;Sayaka Iwata;Mitsuo Hirata;Kazuhiro Mizutani;Shintarou Sayama;Toshiaki Yoshimura;Tsukasa Nakahodo;and Takeshi Akasaka;Takayoshi Fujii
• 通讯作者: Takayoshi Fujii

ビス{ニトリロ[ジ(4-tert-ブチルフェニル)]-λ^6-スルファニル}アミドおよびジイミン配位子を用いた新規ヘテロレプティックPt(II)錯体の合成と発光特性

双{次氮基[二(4-叔丁基苯基)]-λ^6-磺基}酰胺和二亚胺配体新型杂配Pt(II)配合物的合成和发光性能

• 发表时间: 2010
• 作者: Semyon V. Dudkin;Elena A. Makarova;Takamitsu Fukuda;E. A. Lukyanets;Nagao Kobayashi;藤井孝宜
• 通讯作者: 藤井孝宜

日本大学生産工学部応用分子化学科ホームページ

日本大学产业学院应用分子化学系主页

Syntheses and crystal structures of [ClPh_2Sn{E(Ph_2SN)_2}](E=CH,N)

[ClPh_2Sn{E(Ph_2SN)_2}](E=CH,N)的合成及晶体结构

• 发表时间: 2010
• 期刊: Phosphorus, Sulfur andSilicon and the Related Elements
• 作者: Takayoshi Fujii;Sayaka Iwata;Mitsuo Hirata;Kazuhiro Mizutani;Shintarou Sayama;Toshiaki Yoshimura;Tsukasa Nakahodo;and Takeshi Akasaka
• 通讯作者: and Takeshi Akasaka