Exploring Superoxide Chemistry in Clusters
探索簇中的超氧化物化学
基本信息
- 批准号:22550006
- 负责人:
- 金额:$ 3万
- 依托单位:
- 依托单位国家:日本
- 项目类别:Grant-in-Aid for Scientific Research (C)
- 财政年份:2010
- 资助国家:日本
- 起止时间:2010 至 2012
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Reactions of superoxide radicals (O2) in gas-phase clusters were investigatedin terms of the solvent-mediated production of anions having a peroxy form, M-OO〓. We have experimentally demonstrated that the reactivity of O2〓 can be modified significantly by solvation; the yield for the M-OO〓 formation is drastically increased even by a single-molecule solvation. Exploiting the solvent-mediated scheme, we have study the atmospheric chemistry of SO2 and the conversion reaction of O2〓in biological systems.
根据具有过氧形式的溶液介导的阴离子的产生,对超氧化物自由基(O2)的反应进行了研究。我们在实验上证明了O2〓的反应性可以通过溶液显着修改。即使通过单分子溶液,M-OO〓形成的产量也会大大提高。利用溶液介导的方案,我们研究了SO2的大气化学和O2〓In生物系统的转化反应。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
分子-水ネットワークからなる負イオン錯体の構造とクラスター内電子移動ダイナミクス
由分子-水网络组成的负离子配合物的结构和簇内电子传递动力学
- DOI:
- 发表时间:2012
- 期刊:
- 影响因子:0
- 作者:M. Kanno;H. Kono;and Y. Fujimura;中西隆造,永田敬
- 通讯作者:中西隆造,永田敬
Bottom-Up View of Water Network-Mediated CO_2 Reduction Using Cryogenic Cluster Ion Spectroscopy and Direct Dynamics Simulations (Invited Article, Feature Cover Article)
使用低温团簇离子光谱和直接动力学模拟实现水网络介导的 CO_2 还原的自下而上视图(特邀文章,专题封面文章)
- DOI:10.1021/jp209493v
- 发表时间:2012
- 期刊:
- 影响因子:0
- 作者:Kristin J.Breen;et al.
- 通讯作者:et al.
Microhydration Effects on the Intermediates of the SN2 Reaction of Iodide Anion with Methyl Iodide
- DOI:10.1002/anie.201207697
- 发表时间:2013-01-01
- 期刊:
- 影响因子:16.6
- 作者:Doi, Keisuke;Togano, Eijiro;Inokuchi, Yoshiya
- 通讯作者:Inokuchi, Yoshiya
Embryonic Complex Anions ofWater Cluster with Various Molecules
不同分子水团簇的胚胎复合阴离子
- DOI:
- 发表时间:2013
- 期刊:
- 影响因子:0
- 作者:H. Kawasaki;T. Ohshima;T. Ihara;Y. Yagyu;Y. Suda;S. Aoqui;T. Kawasaki;F. Mitsugi;Y. Tajima;T. Baba;Y. Takeuchi;T. Nagata
- 通讯作者:T. Nagata
Hydrogen-Bond Assisted One-Electron Reduction in Water-Network Assemblies
水网络组件中的氢键辅助单电子还原
- DOI:
- 发表时间:
- 期刊:
- 影响因子:0
- 作者:Furukawa Y.;Horiuchi M.;and Kakegawa T.;R. Nakanishi
- 通讯作者:R. Nakanishi
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{{ truncateString('NAGATA Takashi', 18)}}的其他基金
Towards the molecular basis of the ligand-binding mechanism and drug-discovery of TAM receptor tyrosine kinases
TAM 受体酪氨酸激酶配体结合机制和药物发现的分子基础
- 批准号:
23570146 - 财政年份:2011
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Molecular basis for the formation of translational repression complex that regulates stem cell differentiation
调节干细胞分化的翻译抑制复合物形成的分子基础
- 批准号:
20570111 - 财政年份:2008
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Structural Properties of Gas-Phase Solvated Electrons and Anions-Toward the Microscopic Understanding of Stabilization Mechanism-
气相溶剂化电子和阴离子的结构性质-稳定机制的微观理解-
- 批准号:
18550007 - 财政年份:2006
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Development of Novel Reactions in Cluster-Mediated Anion Chemistry
簇介导阴离子化学新反应的发展
- 批准号:
15350006 - 财政年份:2003
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Structures and Reactivities of Negatively-Charged Clusters in Supercritical Carbon Dioxide
超临界二氧化碳中带负电团簇的结构和反应性
- 批准号:
12440160 - 财政年份:2000
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Reaction Control by Cluster-Mediaipd Chemistry
通过簇-Mediaipd 化学控制反应
- 批准号:
11166217 - 财政年份:1999
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research on Priority Areas (A)
A Highly Productive Basin-Type-Multiple-Effect Coupled Solar Still
高产盆式多效耦合太阳能蒸馏器
- 批准号:
10650220 - 财政年份:1998
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (C)
Dynamics of Gas-Phase Clusters as Studied by Tune-Resolved Photoelectron
调谐分辨光电子研究气相团簇动力学
- 批准号:
09440210 - 财政年份:1997
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for Scientific Research (B)
Structures and Dynamics of Negatively-Charged Molecular Clusters
带负电分子团的结构和动力学
- 批准号:
06453015 - 财政年份:1994
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for General Scientific Research (B)
Enhancement of Mass Transfer into a Falling Liquid Film by Two-Dimensional Waves
二维波增强落下液膜的传质
- 批准号:
05650201 - 财政年份:1993
- 资助金额:
$ 3万 - 项目类别:
Grant-in-Aid for General Scientific Research (C)
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