Development of Photoresponsive Functional Biocatalyst

光响应功能生物催化剂的研制

• 批准号: 20550093
• 负责人: SATO Ohki
• 金额: $ 3.24万
• 依托单位: Saitama University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2008
• 资助国家: 日本
• 起止时间: 2008 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20550093/
• 关键词: 機能性触媒; デンドリマー; デンドロンチオール; 多光子捕捉能; 自己組織化; 水溶性; 硫化カドミウム; 分子クラスター; CdS; 配位子交換反応; 加水分解; カルボン酸塩; ジスルフィド; 半導体ナノ粒子; カルボン塩逢; ジスルフド

Chemical and physical properties of CdS nano particles and molecular clusters capping with dendritic ligands are of interest. We designed novel water-soluble dendronthiols as the capping ligands, and succeeded in the synthesis of corresponding first to third generation (G1-G3) dendronthiols by the stepwise method. Synthetic attempts for CdS molecular clusters capping with the dendronthiols were performed by thiol exchange reaction.

CDS纳米颗粒的化学和物理性质与树突状配体限制的分子簇很重要。我们将新型的水溶性树突硫醇设计为盖配体，并通过逐步方法成功地合成了第一代与第三代（G1-G3）树枝状硫醇。用树枝状硫醇限制CDS分子簇的合成尝试是通过硫醇交换反应进行的。

项目成果

One-pot Synthesis of Bromo-tetracyanoazulenequinodimethanes and Conducting Properties of Their Charge Transfer Complexes with Tetratbiotetracene

溴代四氰基薁醌二甲烷的一锅法合成及其与四联四烯的电荷转移配合物的导电性能

• 发表时间: 2009
• 期刊: J. Sulfur Chem. 30(in press)
• 作者: Ohki Sato;M. Sato;H. Sugimoto;T. Kuramochi;T. Shirahhata;and K. Takahashi
• 通讯作者: and K. Takahashi

Complehensive Heterocyclic Chemistry III(Chapter 3.11)

综合杂环化学III（第3.11章）

• 发表时间: 2008
• 作者: Ohki Sato;Juzo Nakayama
• 通讯作者: Juzo Nakayama

Kinetics of Photochromic Induced Energy Transfer between Manganese-Doped Zinc-Selenide Quantum Dots and Spiropyrans

• DOI: 10.1021/jp809797x
• 发表时间: 2009-03-12
• 期刊: JOURNAL OF PHYSICAL CHEMISTRY C
• 影响因子: 3.7
• 作者: Emin, Saim M.;Sogoshi, Norihito;Dushkin, Ceco D.
• 通讯作者: Dushkin, Ceco D.

Reactions of Thiazazulanone and Thiazaulathione with Dimethyl Malonate Derivatives

噻唑蓝酮和噻唑硫酮与丙二酸二甲酯衍生物的反应

• 发表时间: 2009
• 期刊: Abstracts of 22nd International Congress of Heterocyclic Chemistry
• 作者: Ohki Sato;N.Ando;T.Toma;H.Onuma;J.Nakayama
• 通讯作者: J.Nakayama

Synthetic Study of Water soluble Dendronthiols and Their Capped CdS Molecular Clusters

水溶性树枝状硫醇及其封端CdS分子簇的合成研究

• 发表时间: 2011
• 期刊: Abstracts of 23rd International Congress of Heterocyclic Chemistry (in press)
• 作者: Ohki Sato;Y.Horii;C.Nakajima;J.Nakayama
• 通讯作者: J.Nakayama