Chemical Analysis on Polycyclic Aromatic Hydrocarbons and Nitroarenes in Atmosphere in the Area of Pan-Japan Sea, and Removal of these Organic compounds with Iron Oxides

环日本海地区大气中多环芳烃和硝基芳烃的化学分析及氧化铁去除这些有机化合物

• 批准号: 14208073
• 负责人: IWAI Masao
• 金额: $ 31.37万
• 依托单位: Toyama National College of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2002
• 资助国家: 日本
• 起止时间: 2002 至 2004
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14208073/
• 关键词: Polycyclic Aromatec Hydrocarbons; Nitroarenes; Pan-Japan-Sea Area; Atmospheric Environment; Iron Oxides; Catalysis; ニトロ多環芳香族炭化水素; 環日本海域; 燃焼燃料と発生化学; 季節変動; 酸化鉄; 高効率除去; 国際研究者交流; 大気中挙動; 排熱利用; 無害化; 内分泌攪乱物質; PAT; 石炭燃焼; ディーゼルエンジン; 環日本海諸国; フッ

Analysis of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (nitroarenes) in the atmosphere in the area of Pan-Japan-Sea and removal of these organic compounds with iron oxides have been investigated. Concentration of these compounds in the atmosphere of Toyama, Kanazawa, Vladivostok and Shenyang show ed differences in the amount and the composition. The concentration of these organic compounds in Shenyang and her suburb was more than 10 times higher than that in Kanazawa. The ratio of 1-nitropyrene, one of the nitroarenes, to pyrene, one of the PAHs, suggested that main source of these compounds in Shenyang was coal combustion, though in Kanazawa and Toyama the main source is diesels-engine exhaust. Iron oxide (haematite) reacted with these compounds in helium stream at 300 〜 700 ℃ and removed them in the form of blackish particles on the iron oxide, indicating that the iron oxide catalyzed the thermal decomposition of these organic compounds. X-ray study showed that magnetite phase was observed after the reaction of haematite with the organics. This indicates that haematite was partially reduced to magnetite with the organics. By flowing air instead of helium, the organic, compounds were removed completely without forming blackish compounds on iron oxide, suggesting that oxygen in air oxidised the blackish compounds, probably the elementary carbon, and removed from the surface in the form of carbon dioxide. No phase transformation was observed from X-ray analysis of the haematite sample, indicating that haematite was not reduced to magnetite in air stream. Efficiency of removal of nitroarenes were higher than that of PAHs. Induction by nitro group may contributed to enhance the removal efficiency of PAHs.

在泛日 - 海中的多环芳烃（PAHS）和硝化环芳烃（硝化碳烯）的分析，并投资了用氧化铁去除这些有机化合物。这些化合物的浓度在富山，卡纳泽，弗拉迪沃斯托克和雪阳的大气中显示出数量和组成的差异。这些有机化合物在沉阳和她的郊区的浓度是金泽的10倍以上。 1-硝基吡啶（其中一种硝化苯甲酸酯）与PAHS之一的Pyrene的比例表明，这些化合物在Shenyang中的主要来源是煤炭混合物，尽管在Kanazazawa和Toyama中，主要来源是柴油机 - 柴油机 - 发动机排气。氧化铁（赤铁矿）与这些化合物在300至700°C的氦气中反应，并以氧化铁上的黑色颗粒的形式将其除去，表明氧化铁催化了这些有机化合物的热分解。 X射线研究表明，在赤铁矿与有机体反应后观察到磁铁矿相。这表明霍米特石被部分降低至用有机体的磁铁矿。通过流动的空气而不是氦气，可以完全去除化合物，而不会在氧化铁上形成黑色化合物，这表明空气中的氧气是黑色化合物，可能是基本碳，并以二氧化碳形式从表面取出。从X射线样品的X射线分析中未观察到相变，表明在空气流中没有将赤铁矿还原为磁铁矿。去除硝酸的效率高于PAH。 Nitro组的诱导可能有助于提高PAH的去除效率。

项目成果

Tang N., 他: "Improvement of an Automatic HPLC System for Nitropolycyclic Aromatic Hydrocarbons : Removal of an Interfering Peak and Increase in the Number of Analytes"Analytical Science. 19・2. 249-253 (2004)

Tang N.等人：“硝基多环芳香烃自动HPLC系统的改进：干扰峰的去除和分析物数量的增加”分析科学19・2（2004）。

化学発光検出測定-HPLC法測定による大気中ニトロ多環芳香族炭化水素

化学发光检测测量——HPLC法测量大气中硝基多环芳烃

• 发表时间: 2004
• 期刊: 世界科技研究與発展 26(4)
• 作者: Bengea;Simona 他;鴻渡 亮次他;鈴木 登紀子 他;内田 毅 他;Y.Sasakura;S.Bengea;R.Koudo;T.Suzuki;T.Uchida;J.Igarashi;J.Yadav;S.Bengea;M.Moreau;Tang N.;丁子哲治;Tang N.;唐〓
• 通讯作者: 唐〓

Simulateneous determination of twenty-one mutagenic nitropolycyclic aromatic hydrocarbons by high-performance liquid chromatography with chemiluminescence detection

化学发光高效液相色谱法同时测定21种致突变性硝基多环芳烃

• 发表时间: 2005
• 期刊: Luminescence ; the Journal of Biological and Chemical Luminescence (in press)
• 作者: Bengea;Simona 他;鴻渡 亮次他;鈴木 登紀子 他;内田 毅 他;Y.Sasakura;S.Bengea;R.Koudo;T.Suzuki;T.Uchida;J.Igarashi;J.Yadav;S.Bengea;M.Moreau;Tang N.
• 通讯作者: Tang N.

Comparison of Pretreatment Methods for Determination of Polycyclic Aromatic Hydrocarbons in Soil Samples (Japanese)

土壤样品中多环芳烃测定的前处理方法比较（日文）

• 发表时间: 2004
• 期刊: ournal of Ecotechnology Research 10
• 作者: Bengea;Simona 他;鴻渡 亮次他;鈴木 登紀子 他;内田 毅 他;Y.Sasakura;S.Bengea;R.Koudo;T.Suzuki;T.Uchida;J.Igarashi;J.Yadav;S.Bengea;M.Moreau;Tang N.;丁子哲治;Tang N.
• 通讯作者: Tang N.

ろ過式降水採取器により採取された降下物中の黄砂エアロゾルに由来する水溶性化学成分

过滤式沉淀收集器收集的沉降物中来自黄尘气溶胶的水溶性化学成分

• 发表时间: 2004
• 期刊: Journal of Ecotechnology Research 10
• 作者: Bengea;Simona 他;鴻渡 亮次他;鈴木 登紀子 他;内田 毅 他;Y.Sasakura;S.Bengea;R.Koudo;T.Suzuki;T.Uchida;J.Igarashi;J.Yadav;S.Bengea;M.Moreau;Tang N.;丁子哲治
• 通讯作者: 丁子哲治