Kinetical analysis of individual atoms and molecules in the organizing processes on solid surfaces

固体表面组织过程中单个原子和分子的动力学分析

• 批准号: 13650875
• 负责人: INUKAI Junji
• 金额: $ 2.3万
• 依托单位: Tohoku University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2001
• 资助国家: 日本
• 起止时间: 2001 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13650875/
• 关键词: Nanotechnology; Self-organization; Liquid and solid phases; Metal surfaces; Specific adsorbed ions; Compound semiconductor thin films; 自己組織化; 固液界面; 原子・分子レベル; 超高真空; 電気化学; STM; LEED; 単結晶電極表面; 原子分子レベル; 電気化学STM; UPD; 単分子層; 特異吸着アニオン; アントラセン

One basis of the nanotechnology is fabricating surfaces at namometer level. For this process, the self-organization of atoms and molecules is considered as a promising phenomenon. In order to understand the self-organizing processes contributing to nanotechnology at nanometer processes at solid and solid/liquid interfaces, we carried out investigation on four field : 1) Metal surfaces, 2) Specific adsorbed ions, 3) Organic molecules, and 4) Compound semiconductor thin films. For all the topics listed above, the atomic/molecular processes were elucidated.To be more concrete, following topics were made clear: 1) Nanostructuring at Pt surface, 2) Self-organization of specific adsorbed ions, 3) Self-organization of organic molecules, and 4) Fabrication of thin films of compound semiconductors by anordic oxidation.

纳米技术的基础之一是制造纳米级的表面。对于这个过程，原子和分子的自组织被认为是一个有前途的现象。为了了解在固体和固/液界面的纳米过程中对纳米技术做出贡献的自组织过程，我们在四个领域进行了研究：1) 金属表面，2) 特定吸附离子，3) 有机分子，4)化合物半导体薄膜。对于上面列出的所有主题，都阐明了原子/分子过程。更具体地说，明确了以下主题：1）Pt 表面的纳米结构，2）特定吸附离子的自组织，3）有机物的自组织分子，以及4)通过阳极氧化制造化合物半导体薄膜。

项目成果

M.Sugimasa, J.Inukai, K.Itaya: "Structure of Sulfur Adlayer on Cu (111) Electrode in Alkaline Solution"J. Electrochem. Soc.. 150. E110-E116 (2003)

M.Sugimasa、J.Inukai、K.Itaya：“碱性溶液中 Cu(111) 电极上硫吸附层的结构”J。

M.Sngimasa, J.Inukai, K.Itaya: "In situ STM studies of sulfur and thiocyanate adlayers on Cu(111) in alkaline solution"J.Electroanal.Chem.. 554-555. 285-291 (2003)

M.Sngimasa、J.Inukai、K.Itaya：“碱性溶液中 Cu(111) 上硫和硫氰酸盐吸附层的原位 STM 研究”J.Electroanal.Chem. 554-555。

M.Sugimasa, J.Inukai, K.Itaya: "Structure of Sulfur Adlayer on Cu(111) Electrode in Alkaline Solution"J.Electrocham.Soc.. 150. E110-E116 (2003)

M.Sugimasa、J.Inukai、K.Itaya：“碱性溶液中 Cu(111) 电极上硫吸附层的结构”J.Electrocham.Soc.. 150. E110-E116 (2003)

M.Sugimasa, J.Inukai, K.Itaya: "Adlayer Structure of Sulfur on Cu(111) Electrode in Alkaline Solution"J. Electrochem. Soc.. 150(2). E110-E116 (2002)

M.Sugimasa、J.Inukai、K.Itaya：“碱性溶液中 Cu(111) 电极上硫的吸附层结构”J。

T.Shimooka, J.Inukai, K.Itaya: "Adlayer Structures of Cl and Br and Growth of Bulk AgBr Layers on Ag(lOO)Electrodes"J. Electrochem. Soc.. 149. E19-E25 (2002)

T.Shimooka、J.Inukai、K.Itaya：“Cl 和 Br 的吸附层结构以及 Ag(100) 电极上块状 AgBr 层的生长”J。