DEVELOPMENT OF MOLECULAR ACTUATOR BASED ON CONFORMATIONAL TRANSFORMATION

基于构象变换的分子驱动器的开发

• 批准号: 07651113
• 负责人: OISHI Yushi
• 金额: $ 1.28万
• 依托单位: SAGA University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1996
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07651113/
• 关键词: MONOLAYER; POLYOXYMETHYLENE; DIPOLE MOMENT; CONFORMATAION; ACTUATOR; AFM

Recently, development of molecular mashine, acting in a scale of molecular assembly, have started based on usage of probe microsocpy. In this project, we tried to orient uniaxially dipole moments in a polyoxymethylene chain by applying electric field in order to develop a novel actuator (molecular piston).A benzene solution of polyoxymethylene was spread on water surface to prepare the polyoxymethylene monolayr. The monolayr was prepared by changing the concentration of spread solution, the surface pressure, the compression speed and the subphase temperature. The monolayr was transfeercl onto mica substrate to observe the morphology by an atomic force microscope. The morphologically homogeneous polyoxymethylene monolayr was prepared by the compression speed of 0.8 mm/s the surface pressure of 20 mN/m and at the subphase temperature of 293 K by using the solution with the concentration of 10^3 M.An isolated polyoxymethylene chain was obtained by scanning at stronger applied force. The expansion and contraction behaviors of polyoxymethylene chain will be investigated by applying electric field between cantilever and the substrate.

最近，基于探针微社会的使用，以分子组装的量表作用的分子杂种的发展开始。在这个项目中，我们试图通过施加电场来开发新型执行器（Molecular Piston），在聚氧甲基链中单次偶极矩（分子活塞）。多氧甲基的苯溶液在水面上散布在水表面上以制备聚氧甲基烯基元。通过更改扩散溶液的浓度，表面压力，压缩速度和亚相温度来制备单片。将单层转移到云母底物上，以通过原子力显微镜观察形态。通过0.8 mm/s的压缩速度为20 mn/m，在293 K的亚相温度下，通过使用10^3 m.an iman分离的多氧甲基链的溶液在强施加强度的强度时，在293 K的亚相温度下，通过在293 K的亚相温度下，在293 k的亚相温度下，制备了形态上均匀的多氧甲基单甲基。通过在悬臂和底物之间应用电场，将研究聚氧甲基链的膨胀和收缩行为。

项目成果

Yushi Oishi et al.: "Construction of Two-dimensional Single Crystal of Fatty Acid by Two-step Cooling Crystallization Method" Chemistry Letters. (in press).

Yushi Oishi等人：“通过两步冷却结晶法构建脂肪酸二维单晶”化学快报。

Yushi Oishi et al.: "Atomic Force Microscopic Observation of Random Molecular Arrangement in Dialkyl Guanidinium Monolayer" Chemistry Letters. 857-858 (1996)

Yushi Oishi 等人：“二烷基胍单层中分子随机排列的原子力显微镜观察”化学快报。

Y.Oishi,et al.: "Molecular Aggregation State-photo polymerization Behavior Relationship of Lithium 10,12-Heptacosediynoate Monolayer" Langmuir. 11. 3536-3541 (1995)

Y.Oishi 等人：“10,12-庚糖二炔酸锂单层的分子聚集态-光聚合行为关系”Langmuir。

Yushi Oishi et al.: "Morphology and Molecular Orientation and Structure of Langmuir-Blodgert Films of Chlorophyll a Studied by Atomic Fone Microscopy and UV-VIS and IR spectroscopies" Journal of Chemical Society,Faraday Transactions. (in press).

Yushi Oishi 等人：“通过原子丰度显微镜、紫外-可见光和红外光谱研究的叶绿素 a 的 Langmuir-Blodgert 薄膜的形态、分子取向和结构”化学学会杂志，法拉第会刊。

T.Kajiyama,et al.: "Classification for Molecular Aggregation Structure of Monolayers on the water surface" Supramolecular Science.

T.Kajiyama等人：“水面单层分子聚集结构的分类”超分子科学。