Japan-Czech Collaborative Research on Molecular Science

日本-捷克分子科学合作研究

基本信息

批准号：
07044107
负责人：
YOSHIHARA Keitaro
金额：
$ 2.18万
依托单位：
Okazaki National Research Institutes
依托单位国家：
日本
项目类别：
Grant-in-Aid for international Scientific Research
财政年份：
1995
资助国家：
日本
起止时间：
1995 至 1996
项目状态：
已结题

项目摘要

The purpose of the present program has been to have (1) collaborations on selected subjects of molecular science, (2) information exchange seminars, and to discuss (3) a possibility of establishing a collaborative center on molecular science and further development of collaboration between two countries. In 1995 Japanese members visited various educational, research, and government institutions in Czech Republics and discussed the above matters. In 1997 Czech counter partners visited IMS and had an information exchange seminar. Throughout two years we had conducted research by either exchange of persons or of materials and studied on 1) Theoretical and experimental studies on reaction dynamics, 2) Spectroscopic studies on biologically important molecules, 3) Time-resolved studies on molecular dynamics, and 4) Developments on functional molecular materials.Some of the hi-lights of the research program are (a) mechanistic clarification of the proton transfer and hydrogen abstraction in an ion-molecular reaction of acetonitril ion and neutral molecule, (b) theoretical identification of new interesting resonance structure in the collision reaction between electron in HI or DI molecule. (c) the intramolecular energy transfer of some bi-fiuoropher compound has been studied and significant excitation-wavelength dependence was found by the subpicosecond time-resolved spectroscopy, and (d) the mechanism of the photoconductivity of alternatively stacking molecular materials containing tetrathiafulvalene and p-chloranil as an electron acceptor has been clarified.

本计划的目的是（1）关于分子科学的选定学科，（2）信息交流研讨会的合作，并讨论（3）建立分子科学协作中心的可能性，并在两个国家之间的协作进一步发展。 1995年，日本成员访问了捷克共和国的各种教育，研究和政府机构，并讨论了上述问题。 1997年，捷克柜台合作伙伴访问了IMS，并举办了一个信息交流研讨会。在两年中，我们通过交换人员或材料进行了研究，并研究了1）关于反应动力学的理论和实验研究，2）关于生物学上重要分子的光谱研究，3）3）分子动力学的时间分辨研究，以及4）4）在功能分子材料上的发展，该材料的功能分子材料均为蛋白质材料。乙腈离子和中性分子的离子分子反应，（b）HI或DI分子中电子碰撞反应中新有趣的共振结构的理论鉴定。（c）已经研究了某些双菌蛋白化合物的分子内能传递，并通过亚旋转时间分解的光谱镜发现了显着的激发波长依赖性，并且（d）（d）（d）（d）叠加分子材料的光导不传导性的机制，这些分子材料含有四氧化甲烯和p-氯酯和p-氯氯的含量。