Multi-dimentional Analysis of Highly Specific Organic Reactions Governed by the Combinal Influence of Functional Groups

官能团综合影响下的高特异性有机反应的多维分析

• 批准号: 04303002
• 负责人: SUZUKI Hitomi
• 金额: $ 15.62万
• 依托单位: KYOTO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Co-operative Research (A)
• 财政年份: 1992
• 资助国家: 日本
• 起止时间: 1992 至 1993
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-04303002/
• 关键词: Substituent effect; Heteroatom Compounds; Stereochemistry; Asymmetric Synthesis; Kinetics; Photochemical reaction; Electron transfer; Reaction intermediate

Specificity in organic reactions, one of the most important research subjects of current organic chemistry, has been investigated systematically under the name of the title joint project by twenty-eight chemists of a wide variety of speciality backgrounds. The selected experts were devided into three project teams of comparative size ; the first team was mainly concerned with the problems on the enhancement of specificity and reactivity by organic functional groups ; the second one was devoted to the analysis of the relationship between reactivity and electronic requirements, and the last one dealt with the high specificity arising from some functionalized reactive intermediate. The project has brought a great success, more than 460 original papers being published in prestigeous international journals during the given period of the joint studies. Major part of the fruitful results has been presented by the members of each team at two open meetings held in Kyoto on Dec. 4-5, 1993 and Dec. 17-18, 1994.

有机反应的特异性是当前有机化学的最重要的研究主题之一，已被二十八名化学家的各种特色背景的二十八个化学家系统地研究。选定的专家被分为比较规模的三个项目团队。一线队主要关注有机官能团提高特异性和反应性的问题。第二个专门用于分析反应性和电子需求之间的关系，最后一个涉及由某些功能化的反应性中间体引起的高特异性。该项目取得了巨大的成功，在给定的联合研究时期，有460多篇原始论文发表在知名的国际期刊上。每个团队的成员在1993年12月4日至5日在京都举行的两次公开会议上提出了富有成果的结果。

项目成果

Mitsuo Kira: "p-and m-Phenylenebis[trifluoro(phenyl)silicates] and Related Monosilicates" Chem.Lett.1859-1862 (1993)

Mitsuo Kira：“对-和间-亚苯基双[三氟(苯基)硅酸盐]和相关的单硅酸盐”Chem.Lett.1859-1862 (1993)

Mitso Kira: "p-and m-phenylenebis (tri-fluoro (phenyl) silicates) and related Monosilicates" Chem. Lett.1859-1862 (1993)

Mitso Kira：“对-和间-亚苯基双（三氟（苯基）硅酸盐）和相关的单硅酸盐”Chem。

Hideo Tomioka: "Formation of Heptafulvene in Reaction of (Methoxycarbonyl) phenyl carbene in the Gas Phases" J.Am. Chem. Soc.58. 4196-4197 (1993)

Hideo Tomioka：“（甲氧基羰基）苯基卡宾在气相中反应形成庚富烯”J.Am.

Mitsuo Kira: "p- and m-Phenylenebis[trifluoro(phenyl)silicates]and Related Monosilicates" Chem.Lett.1859-1862 (1993)

Mitsuo Kira：“对-和间-亚苯基双[三氟(苯基)硅酸盐]和相关的单硅酸盐”Chem.Lett.1859-1862 (1993)

Hideo Tomioka: "Formation of Heptafulvene in Reaction of [(Methoxycarbonyl)]phenylcarbene in the Gas Phases" J.Am.Chem.Soc.58. 4196-4197 (1993)

Hideo Tomioka：“[(甲氧基羰基)]苯基卡宾在气相中反应形成庚富烯”J.Am.Chem.Soc.58。