Nonlinear Optical Properties of Organic Polymer Films

有机聚合物薄膜的非线性光学特性

• 批准号: 01420016
• 负责人: KODA Takao
• 金额: $ 10.69万
• 依托单位: The University of Tokyo
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (A)
• 财政年份: 1989
• 资助国家: 日本
• 起止时间: 1989 至 1992
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-01420016/
• 关键词: Organic films; Nonlinear Optics; Conjugated Polymers; Polydiacetylenes; Polysilanes; One-Dimensional Excitons; Quantum Wires; 光役系高分子; 一次元励起子モデル; 三次非線形感受率; 第三高調波発生; 薄膜作製技術; 一次元電子状態; 高分子材料; 光導波路; 光クロミズム; 有機高分子; 非線形光学材料; 非線形光学特性

At the first stage of this research project,we have focused our attention on the pi-conjugated polymer,polydiacetylenes. We established the fabrication technique of highly-oriented polydiacetylene films by vacuum deposition in 1987 [1],and extensively investigated the third- order nonlinear optical (NLO) properties of thus obtained films [1-4,10].In the meantime, we developed the simple and accurate method for determining the third-order NLO susceptibility of thin films [6,7].The research objects were extended to other polymers and low dimensional organic molecular crystals. The NLO properties of quasi- one-dimensional platinum compounds [5,8] and copper phthalocyanine [9] have been clarified.The most important results were obtained for o-conjugated silicon polymer,polysilanes [11-14]. The modulus and phase of the complex third-order NLO susceptibility spectra were measured on the polysilane films over a wide photon energy range. From the analysis of the experimental results in terms of the one-dimensional exciton model, the important aspects of NLO processes of polysilanes are elucidated.These researches were summarized in [15].

在该研究项目的第一阶段，我们将注意力集中在π共轭聚合物聚二乙炔上。我们于1987年建立了真空沉积高取向聚二乙炔薄膜的制备技术[1]，并广泛研究了由此获得的薄膜的三阶非线性光学（NLO）性能[1-4,10]。发展了简单而准确的测定薄膜三阶非线性光学磁化率的方法[6,7]。研究对象扩展到其他聚合物和低维有机分子晶体。准一维铂化合物[5,8]和铜酞菁[9]的非线性光学性质已经得到阐明。最重要的结果是在邻共轭硅聚合物、聚硅烷[11-14]上获得的。在较宽的光子能量范围内测量了聚硅烷薄膜上复杂的三阶 NLO 磁化率谱的模量和相位。通过一维激子模型的实验结果分析，阐明了聚硅烷非线性光学过程的重要方面。这些研究总结于[15]。

项目成果

T.Hasegawa,Y.Iwasa,H.Kishida,T.Koda,Y.Tokura,H.Tachibana and Y.Kawabata: "Norlinear Optical Properties of Polysilanes" Molecular Crystals and Liquid Crystals. 217. 25-30 (1992)

T.Hasekawa、Y.Iwasa、H.Kishida、T.Koda、Y.Tokura、H.Tachibana 和 Y.Kawabata：“聚硅烷的非线性光学性质”分子晶体和液晶。

K.Miyano and A.Mori: "A Simple Langmuir Trough for an Inverted Fluorescence Microscope" Japanese Journal of Applied Physics. 28. 252-257 (1989)

K.Miyano 和 A.Mori：“倒置荧光显微镜的简单朗缪尔槽”日本应用物理学杂志。

T.Hasegawa,Y.Iwasa,H.Kishida,T.Koda,T.Tokura,H.Tachibana and Y.Kawabata: "Nonlinear Optical Properties of Polysilanes" Molecular Crystals and Liquid Crystals. 217. 139-145 (1992)

T.Hasekawa、Y.Iwasa、H.Kishida、T.Koda、T.Tokura、H.Tachibana 和 Y.Kawabata：“聚硅烷的非线性光学性质”分子晶体和液晶。

T.Hasegawa,K.Ishikawa,T.Kanetake,T.Koda,K.Takeda,H.Kobayashi,K.Kubodera: "Excitonic Resonance Effect in the Thirdーorder Nonlinear Optical Properties of Blue and Redーform Polydiacetylene Films" Physical Review B.

T. Hasekawa、K. Ishikawa、T. Kanetake、T. Koda、K. Takeda、H. Kobayashi、K. Kubodera：“蓝色和红色聚二乙炔薄膜三阶非线性光学性质中的激子共振效应”物理评论 B .

T.Hasegawa,K.Ishikawa,T.Kanetake,T.Koda,K.Takeda,H.Kobayashi and K.Kubodera: "Excitonic resonant effect in the thirdーorder nonlinear optical properties of blueー and redーform polydiacetylene films" Chemical Physics Letters. 171. 239-244 (1990)

T. Hasekawa、K. Ishikawa、T. Kanetake、T. Koda、K. Takeda、H. Kobayashi 和 K. Kubodera：“蓝色和红色聚二乙炔薄膜三阶非线性光学特性中的激子共振效应”化学物理快报171。239-244（1990）