Microchemistry Based on Single Colloidal and Aerosol Particles

基于单一胶体和气溶胶颗粒的微化学

• 批准号: 23245015
• 负责人: KITAMURA Noboru
• 金额: $ 32.2万
• 依托单位: Hokkaido University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-23245015/
• 关键词: レーザー捕捉; 単一微粒子; コロイド; エアロゾル; マイクロ分析化学; コロイド粒子; レーザー捕捉・顕微分光; 機器分析; 顕微計測; エアロゾル液滴; コロイド液滴; ドナン膜電位

Novel techniques based on laser trapping - microspectroscopy on single micrometer-sized colloidal particles in solution as well as single aerosol water droplets in air have been developed. In particular, we have developed temperature- and moisture-controlled laser trapping of single aerosol water droplets in air. We also confirmed experimentally photoinduced aerosol droplet formation in air and its mechanistic aspects were elucidated. Furthermore, we succeeeded in determining the sizes of single aerosol droplets in a nanometer level based on whipering gallery mode resonances of Raman scattering light in single aerosol droplets. We also showed that the intraparticle diffusion of a cation dye in single cation-exchange resin microparticles was determined by the Donnan electric membrane potential generated at the resin/water interface, which was the first observation for single ion-exchange microparticles.

已经开发了基于激光诱捕的新技术 - 在溶液中的单微米大小的胶体颗粒以及空气中的单烟雾水滴中的微光谱。特别是，我们已经开发了空气中单烟雾水滴的温度和水分控制的激光捕获。我们还证实了空气中的实验光诱导的气溶胶液滴形成，并阐明了其机械方面。此外，我们基于鞭子库模式在单个气溶胶液滴中的拉曼散射光的共振，在纳米水平上取消了在纳米水平上确定单气溶胶液滴的大小。我们还表明，阳离子染料在单个阳离子交换树脂微粒中的颗粒内扩散是由在树脂/水界面上产生的Donnan电膜电位确定的，这是单个离子 - 换量微粒的首次观察。

项目成果

Dynamic Emission Quenching of a Novel Ruthenium(II) Complex by Carbon Dioxide in Solution

溶液中二氧化碳对新型钌(II)配合物的动态发射猝灭

• 发表时间: 2012
• 期刊: RSC Advances
• 影响因子: 3.9
• 作者: N. M. Cuong;S. Ishizaka;N. Kitamura;E. Sakuda
• 通讯作者: E. Sakuda

A Laser Trapping and Spectroscopy of Single Supercooled Water Droplets in Air

空气中单个过冷水滴的激光捕获和光谱分析

• 发表时间: 2011
• 作者: Abul K.Mallik;Kaori Shingo;Aika Ezaki;Tsuyoshi Sawada;Makoto Takafuji;Hirotaka Ihara;Shoji Ishizaka
• 通讯作者: Shoji Ishizaka

Laser Trapping-Microspectroscopy of Single Aerosol Droplets in Air

空气中单个气溶胶液滴的激光捕获显微光谱

• 发表时间: 2011
• 作者: Jian Zhao;Naoki Asao;Yoshinori Yamamoto;Tienan Jin;N. Kitamura
• 通讯作者: N. Kitamura

Spectroscopic Study on the Photoinduced Decarboxylation Mechanisms of Synthetic Pyrethroids

合成拟除虫菊酯光致脱羧机理的光谱研究

• 发表时间: 2012
• 期刊: Photochemical and Photobiological Sciences
• 影响因子: 3.1
• 作者: J. T. Lau;K. Hirsch;V. Zamudio-Bayer;A. Langenberg;M. Niemeyer;M. Kossick;B. Langbehn;A. Terasaki;T. Moller;and B. von Issendorff;Y. Suzuki
• 通讯作者: Y. Suzuki

A laser trapping and spectroscopy study on photoinduced water droplets formation in air

空气中光致水滴形成的激光捕获和光谱研究

• 发表时间: 2011
• 作者: Kian Ping Gan;Masafumi Yoshio;Takashi Kato;Shoji Ishizaka
• 通讯作者: Shoji Ishizaka