On Set and Control of Cellular Patterns in Organic-Inorganic Hybrid Film

有机-无机杂化薄膜中泡孔图案的设定与控制

• 批准号: 11450243
• 负责人: SHIBATA Shuichi
• 金额: $ 9.34万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 1999
• 资助国家: 日本
• 起止时间: 1999 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-11450243/
• 关键词: Cellular pattern; Organic-inorganic hybrid film; Influence of moisture; Nanoparticle; Marangoni convection; Thickness of the film; Amino group; 超粒子; ジルコニア; ハイブリッド膜; 深度による発現

Organic-inorganic film of several micrometers in thickness has been investigated. The films fabricated by dipping technique showed the remarkable cellular patterns, when such reagents as Ti, Zr alkoxides and silane coupling agent having amino groups (aminopropyltrimethoxysilane : APTS) were involved in the starting sol.In this investigation, to make clear the condition of on set of the cellular patterns, optical properties of the sol, observation of the film surfaces by laser microscopy and atomic force microscopy (AFM) have been carries out. The results were summarized as follows,(1) Moisture in the atmosphere is inevitable for the onset of the cellular patterns.(2) Along with the hydration-polymerization reaction, nanometer-sized particles were formed in the starting sol and they were grown with increasing the reaction time.(3) The 3-D image of the cell was obtained by the AFM observation. The cell was composed of the valley center surrounded by the mountain- like wall of few nanometer 〜hundred of nanometer. There were the relations between their clearness and the depth.(4) The formation mechanism of the cell in the hybrid film is : the first step is nanometer-sized particles (TiO_2, ZrO_2 or SiO_2 nanoparticles) generation in the starting sol, the second step is the flow of these nanoparticles by the Marangoni convection.

已经研究了几微米的有机无机膜。通过浸入技术制作的膜显示出显着的细胞图案，当Ti，Zr烷氧化物和硅烷偶联剂等试剂中具有氨基群（氨基丙基三甲氧基硅烷：APTS）涉及起始Sol。显微镜（AFM）已进行。结果总结如下：（1）细胞模式的发作不可避免地是大气中的水分。（2）以及水合聚合反应，在起始溶胶中形成纳米尺寸的颗粒，并随着AFM观察而增加了细胞的3-D图像。该细胞由山谷中心组成，周围是几纳米的山脉壁，〜数百纳米。 （4）杂交膜中细胞的形成机理是：第一步是：第一步是纳米尺寸的颗粒（TIO_2，ZRO_2，ZRO_2或SIO_2纳米颗粒）在开始溶胶中的产生，第二步是Marangoni的第二步是这些纳米颗粒的流动。

项目成果

S.Shibata, K.Miyajima, H.Yoshikawa T.Yano, M.Yamane: "Cellular Patterns in Organic-Inorganic Hybrid Film"J.Sol-Gel Science & Tech.. 19. 665-669 (2000)

S.Shibata、K.Miyajima、H.Yoshikawa T.Yano、M.Yamane：“有机-无机杂化薄膜中的细胞图案”J.Sol-Gel Science

Shuichi Shibata, Keita Miyajima, Teruo Kobayashi, Hidemi Yoshikawa, Tetsuji Yano, Masayuki Yamane: "Formation of Cellular Patterns in Hybrid Film"Proceeding of the 39nd Symposium on Glass and Photonic Materials A-35. (1998)

Shuichi Shibata、Keita Miyajima、Teruo Kobayashi、Hidemi Yoshikawa、Tetsuji Yano、Masayuki Yamane：“混合薄膜中蜂窝图案的形成”第 39 届玻璃和光子材料研讨会论文集 A-35。

S.Shibata,K.Miyajima,H.Yoshikawa T.Yano and M.Yamane: "Cellular Patterns in Organic-Inorganic Hybrid Film"J.Sol-Gel Science & Tech.. 19. 665-669 (2000)

S.Shibata、K.Miyajima、H.Yoshikawa T.Yano 和 M.Yamane：“有机-无机混合薄膜中的细胞图案”J.Sol-Gel Science

柴田修一, 宮嶋圭太, 小林照夫, 吉川英見, 矢野哲司, 山根正之: "有機・無機ハイブリッド膜におけるセル構造の発現"第39回ガラスおよびフォトニクス材料討論会予稿集. A-35 (1988)

Shuichi Shibata、Keita Miyajima、Teruo Kobayashi、Eimi Yoshikawa、Tetsuji Yano、Masayuki Yamane：“有机-无机杂化薄膜中细胞结构的表达”第 39 届玻璃和光子材料会议 A-35 会议记录（1988 年）。

柴田修一: "有機・無機ハイブリッド材料"応用物理. 68・1. 20-25 (1999)

柴田秀一：“有机-无机杂化材料”应用物理学68・1（1999）。