Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry

有机和无机化学中二硼烷和四卤二硼烷的路易斯碱活化

• 批准号: 396769488
• 负责人: Professor Dr. Holger Braunschweig
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/396769488?language=en
• 关键词: Lewis; Base; Activation; Di; Tetrahalodiboranes

Over the last decade, the element boron has moved to the forefront of synthetic organic chemistry and the industries that depend on it, including the pharmaceutical, agrochemical, and fine chemical industries. This progress would have been impossible without one key family of inorganic molecules: diboranes. This proposal takes aim at two less well-studied examples of diboranes: di- and tetrahalodiboranes. The chemistry of these compounds, despite their long history, is still poorly understood due to their inherent reactivity. However, the potential benefits of further work with these reactive and unpredictable complexes is vast, both to inorganic and organic chemistry.

在过去的十年中，硼硼已移至合成有机化学和依赖于其的行业的最前沿，包括药物，农业化学和精细的化学工业。没有一个关键的无机分子家族：二曲烷。该提案针对的是两个不太研究的二曲烷的例子：二北di虫和四分法。这些化合物的化学虽然历史悠久，但由于它们的固有反应性，仍然很少理解。但是，与这些反应性和不可预测的复合物进行进一步合作的潜在好处是无机和有机化学的巨大的。