Exploring gate-opening metal-organic polyhedra towards processable porous materials

探索可加工多孔材料的开口金属有机多面体

• 批准号: 19K05495
• 负责人: CRAIG Gavin
• 金额: $ 2.75万
• 依托单位: Kyoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2019
• 资助国家: 日本
• 起止时间: 2019-04-01 至 2020-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-19K05495/
• 关键词: Coordination chemistry; Porous materials; Metal-organic polyhedra; Gas sorption; Crystallography; Supramolecular chemistry; Porous molecular solids; Switchable materials; Inorganic Chemistry

During the course of the funding, we made significant progress in the work packages WP 1 and WP 2 from the proposal: new metal-organic polyhedra showing cooperative behaviour were developed, and they were characterised using single crystal X-ray diffraction, powder diffraction, and by gas sorption measurements. Currently, a draft publication is in preparation and will be submitted shortly (anticipated to be September 2019).I also attended the 14th International Symposium on Macrocyclic and Supramolecular Chemistry 2019, in Lecce, Italy. There, I presented a poster on some of the initial results of the project, met collaborators (Prof. C. J. Doonan, University of Adelaide, Australia), and saw talks on the latest research in soft matter, which is a potential application for our materials.

在资助过程中，我们在提案中的工作包 WP 1 和 WP 2 方面取得了重大进展：开发了具有协同行为的新型金属有机多面体，并使用单晶 X 射线衍射、粉末衍射、并通过气体吸附测量。目前，出版物草案正在准备中，将于近期提交（预计2019年9月）。我还参加了2019年在意大利莱切举行的第14届大环与超分子化学国际研讨会。在那里，我展示了该项目的一些初步结果的海报，会见了合作者（澳大利亚阿德莱德大学的 C. J. Doonan 教授），并观看了有关软物质最新研究的演讲，这是我们材料的潜在应用。

项目成果

Tunable Gate-Opening Gas Uptake in Metal-Organic Polyhedra

金属有机多面体中可调节的开门气体吸收

• 发表时间: 2019
• 作者: Gavin Craig

Reversible Discrete-to-Extended Metal-Organic Polyhedra Transformation by Sulfonic Acid Surface Functionalization.

通过磺酸表面功能化实现离散到扩展金属有机多面体的可逆转变。

• DOI: 10.1021/jacs.2c07978
• 发表时间: 2022-10-12
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: Javier Troyano;S. Horike;S. Furukawa
• 通讯作者: S. Furukawa