Design of hierarchically ordered porous materials by two photon polymerisation of resins containing coordination polymers

通过含配位聚合物的树脂的两次光子聚合设计分级有序多孔材料

• 批准号: 281084610
• 负责人: Professor Dr. Peter Behrens (†)
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2015
• 资助国家: 德国
• 起止时间: 2014-12-31 至 2015-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/281084610?language=en
• 关键词: Design; hierarchically; ordered; porous; materials

Aim of the proposed project is to engineer the direct assembly of hierarchically ordered porous materials by two photon polymerization (2PP). To achieve this, a new class of resin compounds will be explored. The resins, that are structured during the 2PP contain nanoporous MOF nanoparticels. The latter are functionalized to allow the proper embedding in a polymer matrix. This strategy allows the fabrication of nanocomposit materials containing nano- and macropores. The resulting materials will be characterized by common methods, especially sorption measurements with regard to the accessability of the nanopores

拟议项目的目的是通过两种光子聚合（2pp）直接组装层次有序的多孔材料。为了实现这一目标，将探索新的树脂化合物。在2PP期间结构的树脂包含纳米多孔MOF纳米骨化物。后者进行功能化，以允许在聚合物基质中正确嵌入。该策略允许制造含有纳米和大孔的纳米复合材料。所得的材料将以常见方法为特征，尤其是关于纳米孔可及性的吸附测量值