MRI: Acquisition of an Inductively Coupled Plasma Triple Quadrupole mass Spectrometer Instrument for Southeast Louisiana

MRI：为路易斯安那州东南部购买电感耦合等离子体三重四极杆质谱仪

• 批准号: 2018417
• 负责人: Phoebe Zito
• 金额: $ 32.61万
• 依托单位: University of New Orleans
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-09-01 至 2023-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2018417&HistoricalAwards=false
• 关键词: MRI; Acquisition; Inductively; Coupled; Plasma

This award is supported by the Major Research Instrumentation and the Chemistry Research Instrumentation programs. The University of New Orleans is acquiring an inductively coupled, triple quadrupole, mass spectrometer (ICP-triple Q-MS) with laser ablation capabilities to support the research programs of Professor Phoebe Zito and colleagues Matthew Tarr, David Podgorski, Viktor Poltavets and Robert Mahon. In general, mass spectrometry (MS) is one of the key analytical methods used to identify and characterize small quantities of chemical species in complex samples. An ICP-MS combines a high-temperature and an ionization coupled plasma source with a mass spectrometer. The ICP source converts the atoms of the elements in the sample to ions. These ions are subsequently separated and detected by the mass spectrometer. This is a highly-sensitive analytical technique capable of measuring very low concentrations of metals and non-metals in liquid samples. The acquisition strengthens the research infrastructure at the university and regional area. The instrument broadens participation by involving diverse students with this modern analytical technique. It is also used in outreach activities involving students and faculty from Louisiana State University, Southeastern Louisiana University, the Louisiana Universities Marine Consortium, the University of Alaska-Anchorage, Southwest Engineers and other area institutions.The award of the mass spectrometer is aimed at enhancing research and education at all levels. It especially impacts the identification of isotopic compositions to improve the geologic record and the analyzes of clay sources for pottery in the archaeology field. The instrumentation is also used for detecting synergistic effects of nanoparticles in the environment and for identifying metals and their concentrations from natural and human impacted aquatic and terrestrial ecosystems. In addition, it contributes to the determination of calcium rich deposits in fishes, shelled invertebrates, and coralline algae and the measurement of contaminants in fishes, and organisms at the base of food webs with trace elements such as arsenic and cadmium. The mass spectrometer is also used to search for innovative approaches and alternatives for renewable/rechargeable batteries with industrial partners. The ICP spectrometer is also employed for analyses of trace elements bound to organic matter and other petroleum complexes altering toxicity, biotic and abiotic reactivity, and contamination in aquatic water bodies.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该奖项由主要研究仪器和化学研究仪器项目支持。新奥尔良大学正在购买一台具有激光烧蚀功能的电感耦合三重四极杆质谱仪 (ICP-triple Q-MS)，以支持 Phoebe Zito 教授及其同事 Matthew Tarr、David Podgorski、Viktor Poltavets 和 Robert Mahon 的研究项目。一般来说，质谱 (MS) 是用于识别和表征复杂样品中少量化学物质的关键分析方法之一。 ICP-MS 将高温电离耦合等离子体源与质谱仪结合在一起。 ICP 源将样品中元素的原子转换为离子。这些离子随后被质谱仪分离和检测。这是一种高灵敏度的分析技术，能够测量液体样品中极低浓度的金属和非金属。此次收购加强了大学和地区的研究基础设施。该仪器通过让不同的学生参与这种现代分析技术来扩大参与范围。它还用于涉及路易斯安那州立大学、东南路易斯安那大学、路易斯安那大学海洋联盟、阿拉斯加大学安克雷奇分校、西南工程​​师和其他地区机构的学生和教师的外展活动。该质谱仪的获奖旨在增强各级的研究和教育。它尤其影响同位素组成的鉴定，以改善考古领域的地质记录和陶器粘土来源的分析。该仪器还用于检测环境中纳米颗粒的协同效应，以及识别受自然和人类影响的水生和陆地生态系统中的金属及其浓度。此外，它还有助于测定鱼类、带壳无脊椎动物和珊瑚藻中富含钙的沉积物，以及测量鱼类和食物网底部生物体中砷和镉等微量元素的污染物。质谱仪还用于与工业合作伙伴一起寻找可再生/可充电电池的创新方法和替代品。 ICP 光谱仪还用于分析与有机物和其他石油复合物结合的微量元素，这些元素会改变水生水体中的毒性、生物和非生物反应性以及污染。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力价值和更广泛的影响审查标准。

项目成果

Photodissolution of Rare Earth Elements and Dissolved Organic Carbon from Subbituminous Coal: Effects of Environmental Variables and Implications for Biogeochemical Cycling

次烟煤中稀土元素和溶解有机碳的光溶解：环境变量的影响及其对生物地球化学循环的影响

• DOI: 10.1021/acs.estlett.3c00545
• 发表时间: 2023-08-11
• 期刊: Environmental Science & Technology Letters
• 作者: Maxwell L. Harsha;Elizabeth A. Whisenhant;Deja Hebert;Janelle Y. Do;C. Pham;P. Zito;D. Podgorski;P. Tomco
• 通讯作者: P. Tomco

Single-Particle ICP-MS/MS Application for Routine Screening of Nanoparticles Present in Powder-Based Facial Cosmetics

单颗粒 ICP-MS/MS 在粉末面部化妆品中纳米颗粒常规筛查中的应用

• DOI: 10.3390/nano13192681
• 发表时间: 2023-09-30
• 期刊: Nanomaterials
• 影响因子: 5.3
• 作者: Hebert D;Nelson J;Diehl BN;Zito P
• 通讯作者: Zito P