Fundamental Insights into Direct Optical Lithography of Functional Inorganic Nanomaterials (DOLFIN)

功能无机纳米材料直接光学光刻的基本见解 (DOLFIN)

基本信息

批准号：
1905290
负责人：
Dmitri Talapin
金额：
$ 45万
依托单位：
University of Chicago
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2019
资助国家：
美国
起止时间：
2019-08-01 至 2023-07-31
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1905290&HistoricalAwards=false
关键词：
Fundamental Insights into Direct Optical

项目摘要

Professor Dmitri Talapin of the University of Chicago conducts research to develop new chemical reactions to prepare materials that enable simple and precise fabrication of light emitting devices (LEDs) and displays. The goal is to remove the bottleneck between the development of the individual components and the integration in real-world applications. Displays and other optical/electronic devices represent multibillion-dollar markets, and the ability to provide a new universal manufacturing platform for these industries may have significant societal impact. This project helps train students at the interdisciplinary interface of nanoscience, inorganic chemistry, and materials engineering. Furthermore, Professor Talapin partners with the Leadership Alliance to recruit minority and underrepresented undergraduate students. This project also supports interactive summer workshops on nanomanufacturing-related topics for local underrepresented African-American and Hispanic K-12 populations on Chicago's South Side. Professor Talapin is supported by the Macromolecular, Supramolecular, and Nanochemistry Program of the NSF Division of Chemistry to expand upon a new method for direct optical lithography of functional inorganic nanomaterials (DOLFIN). This method uses inorganic nanocrystals with novel photochemically-active surface ligands. The DOLFIN process combines multiple benefits of photolithography and is tailored toward efficient patterning of inorganic nanomaterials without diluting or contaminating them with organic photoresists and other byproducts. DOLFIN is meant to remedy the lack of efficient methods for high-quality additive patterning of solution-processed electronic materials. The range of materials that can be patterned using this technique includes metals, semiconductors, oxides, and magnetic or rare earth compositions. The project goals include the development of new DOLFIN ligands for nanocrystals to expand the range of photon energies and enable multicolor lithography. The team investigates optically triggered reaction pathways and excited-state dynamics in nanocrystal-ligand combinations to reveal the processes responsible for DOLFIN's resolution and sensitivity. The ability to directly pattern functional all-inorganic layers with nanoscale resolution provides an alternate route for thin-film device manufacturing.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

芝加哥大学的Dmitri Talapin教授进行了研究，以开发新的化学反应，以制备材料，以实现简单而精确的发光设备（LED）和展示。目的是消除单个组件的开发与现实应用程序中的集成之间的瓶颈。展示和其他光学/电子设备代表数十亿美元的市场，为这些行业提供新的通用制造平台的能力可能会产生重大的社会影响。该项目可帮助培训学生在纳米科学，无机化学和材料工程的跨学科接口上培训学生。此外，塔拉平教授与领导联盟合作，招募少数民族和代表性不足的本科生。该项目还支持有关当地代表性不足的非裔美国人和西班牙裔K-12人群的纳米制造相关主题的互动夏季研讨会。 NSF化学部的大分子，超分子和纳米化学计划支持塔拉平教授，以扩展一种新方法，用于直接光刻无机纳米材料（Dolfin）。该方法将无机纳米晶体带有新型的光化学表面配体。 Dolfin过程结合了光刻的多个好处，并针对无机纳米材料的有效图案定制，而无需稀释或污染有机光孔师和其他副产品。 Dolfin旨在纠正缺乏有效的方法来解决解决方案加工的电子材料的高质量添加模式。可以使用此技术进行图案的材料范围包括金属，半导体，氧化物以及磁或稀土成分。项目目标包括开发用于纳米晶体的新Dolfin配体，以扩大光子能量范围并启用多色光刻。该小组研究了纳米晶体配体组合中的光学触发反应途径和激发态动力学，以揭示导致Dolfin分辨率和灵敏度的过程。通过纳米级分辨率直接对功能性的全无机层进行模拟的能力为薄膜设备制造提供了替代途径。该奖项反映了NSF的法定任务，并通过使用该基金会的知识分子优点和更广泛的影响审查标准来评估NSF的法定任务。

项目成果

期刊论文数量（14）

专著数量（0）

科研奖励数量（0）

会议论文数量（0）

专利数量（0）

SAS PDF: pair distribution function analysis of nanoparticle assemblies from small-angle scattering data

SAS PDF：根据小角度散射数据对纳米颗粒组件进行对分布函数分析

DOI：
10.1107/s1600576720004628
发表时间：
2020
期刊：
Journal of Applied Crystallography
影响因子：
6.1
作者：
Liu, Chia-Hao;Janke, Eric M.;Li, Ruipen;Juhás, Pavol;Gang, Oleg;Talapin, Dmitri V.;Billinge, Simon J.
通讯作者：
Billinge, Simon J.

Observation of biexciton emission from single semiconductor nanoplatelets