Investigating the Competition Between Exciton Delocalization and Radiative Recombination in 1D Semiconductor Quantum Wires

研究一维半导体量子线中激子离域与辐射复合之间的竞争

• 批准号: 1611149
• 负责人: Richard Loomis
• 金额: $ 41.68万
• 依托单位: Washington University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-07-01 至 2019-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1611149&HistoricalAwards=false
• 关键词: Investigating; Competition; Between; Exciton; Delocalization

Nontechnical Description: One-dimensional semiconductor wires with lengths longer than micrometers can efficiently absorb light that in turn generates mobile charge carriers within the semiconductor. When the diameters of these materials become small, on the order of nanometers to tens of nanometers, both the colors of the light that are preferentially absorbed and the energies of the charge carriers within the semiconductor material can be manipulated. These one-dimensional materials are called semiconductor nanowires, and they represent the smallest structures that can efficiently generate and transport charges along specific directions. The main goal of this interdisciplinary research project is to characterize the efficiency of semiconductor nanowires in terms of charge-carrier generation and transport. An emphasis is placed on optimizing the chemical and physical properties of semiconductor nanowires so their viability in application designs can be evaluated. The research uses both traditional optical spectroscopy and advanced laser techniques to probe the energies of the charge carriers within the nanowires and to characterize the fate of these charge carriers as a function of time and position along single nanowire. Particular attention is given to measuring how well the charge carriers are transported along the length of the nanowires. Another focus of this project is on training the next generation of scientists, especially those from underrepresented backgrounds with diverse expertise in materials science, chemistry, and physics. Technical Description: This research is focused on optimizing the properties of semiconductor quantum wires synthesized by using the solution-liquid-solid strategy with a particular focus on cadmium telluride and cadmium selenide quantum wires. The research team is performing absorbance and photoluminescence spectroscopy experiments to characterize the energies of charge carriers photo-generated within them as well as the photoluminescence quantum yields of the these nanostructures. The dynamics of the electrons, holes, and excitons within the quantum wires are characterized by performing photoluminescence lifetime and transient absorption spectroscopy experiments. Specific goals include: 1) characterization of the exciton lifetime dependences on photoluminescence quantum yield, surface passivation and structural quality of the quantum wires; 2) measurement of exciton diffusion length along single quantum wires and its dependence on photoluminescence quantum yield, surface passivation and quantum wire structural quality; and 3) investigation of the apparent competition between efficient exciton diffusion and the probability for radiative recombination within the quantum wires.

非技术描述：长度超过微米的一维半导体线可以有效吸收光，进而在半导体内产生移动电荷载流子。当这些材料的直径变小时，在纳米到几十纳米的数量级上，优先吸收的光的颜色和半导体材料内电荷载流子的能量都可以被操纵。这些一维材料被称为半导体纳米线，它们代表了能够沿特定方向有效产生和传输电荷的最小结构。这个跨学科研究项目的主要目标是表征半导体纳米线在电荷载流子生成和传输方面的效率。重点是优化半导体纳米线的化学和物理特性，以便评估它们在应用设计中的可行性。该研究使用传统的光谱学和先进的激光技术来探测纳米线内电荷载流子的能量，并将这些电荷载流子的命运描述为沿单根纳米线的时间和位置的函数。特别注意测量载流子沿纳米线长度传输的情况。该项目的另一个重点是培训下一代科学家，特别是那些来自代表性不足的背景、在材料科学、化学和物理方面拥有不同专业知识的科学家。技术描述：本研究重点优化采用溶液-液-固策略合成的半导体量子线的性能，特别关注碲化镉和硒化镉量子线。研究小组正在进行吸光度和光致发光光谱实验，以表征其中光生电荷载流子的能量以及这些纳米结构的光致发光量子产率。通过进行光致发光寿命和瞬态吸收光谱实验来表征量子线内电子、空穴和激子的动力学。具体目标包括：1）表征激子寿命对光致发光量子产率、表面钝化和量子线结构质量的依赖性； 2）沿着单量子线的激子扩散长度的测量及其对光致发光量子产率、表面钝化和量子线结构质量的依赖性； 3）研究有效激子扩散与量子线内辐射复合概率之间的明显竞争。

项目成果

Methods for the ICP-OES Analysis of Semiconductor Materials

半导体材料的 ICP-OES 分析方法

• DOI: 10.1021/acs.chemmater.0c00255
• 发表时间: 2020-03
• 期刊: Chemistry of Materials
• 影响因子: 8.6
• 作者: Morrison, Calynn;Sun, Haochen;Yao, Yuewei;Loomis, Richard A.;Buhro, William E.
• 通讯作者: Buhro, William E.

Intraband Relaxation Dynamics of Charge Carriers within CdTe Quantum Wires

CdTe 量子线内电荷载流子的带内弛豫动力学

• DOI: 10.1021/acs.jpclett.0c01326
• 发表时间: 2020-06
• 期刊: The Journal of Physical Chemistry Letters
• 作者: Sanderson, William M.;Wang, Fudong;Schrier, Joshua;Buhro, William E.;Loomis, Richard A.
• 通讯作者: Loomis, Richard A.

Excitation Energy Dependence of Photoluminescence Quantum Yields in Semiconductor Nanomaterials with Varying Dimensionalities

不同维度的半导体纳米材料中光致发光量子产率的激发能量依赖性

• DOI: 10.1021/acs.jpclett.0c00489
• 发表时间: 2020-05
• 期刊: The Journal of Physical Chemistry Letters
• 作者: Sanderson, William M.;Hoy, Jessica;Morrison, Calynn;Wang, Fudong;Wang, Yuanyuan;Morrison, Paul J.;Buhro, William E.;Loomis, Richard A.
• 通讯作者: Loomis, Richard A.