RUI: Intramolecular Halogen Bonding in Arylene Ethynylene Structures

RUI：亚芳基亚乙炔结构中的分子内卤素键

• 批准号: 1306284
• 负责人: Nathan Bowling
• 金额: $ 24.82万
• 依托单位: University of Wisconsin-Stevens Point
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-06-15 至 2016-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1306284&HistoricalAwards=false
• 关键词: RUI; Intramolecular; Halogen; Bonding; Arylene

With the support from the Macromolecular, Supramolecular and Nanochemistry Program of the Chemistry Division, Professor Bowling of University of Wisconsin-Stevens Point and Professor Bosch of Missouri State University conduct collaborative research to study the spatial and electronic requirements for intramolecular halogen bonding in solution and the solid state, respectively. Specially, the research team investigates the ability of pyridine-halogen attractions to serve as surrogates for alkynes in dehydroannulene-type materials and the feasibility of extending this strategy to more complex macromolecular species. This research aims to develop strategies for incorporating halogen bonding as a tool for conformation control in conjugated molecules. Conjugated organic molecules are important constituents of functional materials in many useful applications. This research contributes both to increasing our fundamental knowledge and the development of alternative synthetic routes to complex structures with potential applications as functional materials. In addition, this project provides research opportunities to undergraduate students, preparing them for industrial positions and graduate studies.

在化学部的大分子，超分子和纳米化学计划的支持下，威斯康星大学 - 斯蒂文斯·波​​特（University of Wisconsin-Stevens Point）的保龄球教授和密苏里州立大学大学的博世教授进行了合作研究，以研究分别针对解决方案和固体状态的分子内卤素内键合的空间和电子要求。 特别是，研究小组调查了吡啶 - 降低吸引力在脱氢氨型材料中用作炔烃替代物的能力，并将这种策略扩展到更复杂的大分子分子物种的可行性。 这项研究旨在制定将卤素键合成作为共轭分子中构象控制的工具的策略。 在许多有用的应用中，共轭有机分子是功能材料的重要组成部分。 这项研究既有助于提高我们的基本知识，又有助于使用潜在应用作为功能材料的复杂结构的替代合成途径。 此外，该项目为本科生提供了研究机会，为他们准备工业职位和研究生研究。