Azulene-bridged Organometallics: New Platforms for Charge Delocalization and Transport at the Nanoscale

甘菊桥有机金属化合物：纳米尺度电荷离域和传输的新平台

• 批准号: 1214102
• 负责人: Mikhail Barybin
• 金额: $ 36万
• 依托单位: University of Kansas Center for Research Inc
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2012
• 资助国家: 美国
• 起止时间: 2012-09-01 至 2016-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1214102&HistoricalAwards=false
• 关键词: Azulene; bridged; Organometallics; New; Platforms

This project funded by the Macromolecular, Supramolecular and Nanochemistry Program of the Chemistry Division, Professor Mikhail Barybin of the University of Kansas will study charge delocalization and transport within the 2,6-azulenic framework. The approach is to synthesize novel azulenic and bis-azulenic molecules linearly terminated with isocyano, mercapto, or cyano groups; to form and characterize self-assembled monolayer (SAM) films and nanografted patterns of these compounds on metal surfaces; to synthesize and study discrete metal complexes of these ligands to understand the ligand interactions with metal ions; and to probe the conductivity of the azulenic and bis-azulenic SAM films The broader impacts involve training undergraduate and graduate students in an interdisciplinary research environment, developing a new freshman honors course on the "Nanotech Revolution," and working with Northeastern State University (a predominantly Native American student institution) to bring students to the University of Kansas for undergraduate research experiences.Computing using molecules has the potential to generate ultrasmall devices that use little power; however, many significant technical hurdles must be overcome to realize the benefits of molecular level devices. This work will further our understanding how molecules transport charges between two contacts and will afford novel platforms for developing advanced materials relevant to a variety of nanotechnological areas, including organic electronics. Such work could also impact the design of solar cells, molecular switches, and conducting polymers.

该项目由化学部高分子、超分子和纳米化学项目资助，堪萨斯大学Mikhail Barybin教授将研究2,6-azulenic框架内的电荷离域和传输。该方法是合成以异氰基、巯基或氰基线性封端的新型甘菊环和双甘菊环分子；形成并表征自组装单层 (SAM) 薄膜以及这些化合物在金属表面上的纳米接枝图案；合成和研究这些配体的离散金属配合物，以了解配体与金属离子的相互作用；更广泛的影响包括在跨学科研究环境中培训本科生和研究生、开发关于“纳米技术革命”的新新生荣誉课程以及与东北州立大学（主要是美国原住民学生机构），将学生带到堪萨斯大学进行本科研究体验。使用分子进行计算有可能产生耗电量极小的超小型设备；然而，要实现分子水平器件的优势，必须克服许多重大的技术障碍。 这项工作将进一步了解分子如何在两个触点之间传输电荷，并将为开发与各种纳米技术领域（包括有机电子学）相关的先进材料提供新的平台。 此类工作还可能影响太阳能电池、分子开关和导电聚合物的设计。

项目成果

Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

调整2-异氰甘菊配体的α-受体/α-供体比例：发现五氟苯基异氰化物和三氟乙烯基异氰化物的非氟化竞争对手

• DOI: 10.3390/molecules26040981
• 发表时间: 2021-02-12
• 期刊: Molecules
• 影响因子: 4.6
• 作者: Hart MD;Meyers JJ Jr;Wood ZA;Nakakita T;Applegate JC;Erickson NR;Gerasimchuk NN;Barybin MV
• 通讯作者: Barybin MV