International Collaborative Photoionization Study of Heats of Formation and Bond Energies of Organometallic Complexes

有机金属配合物的生成热和键能的国际合作光电离研究

• 批准号: 0743000
• 负责人: Tomas Baer
• 金额: $ 23.17万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-07-15 至 2012-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0743000&HistoricalAwards=false
• 关键词: International; Collaborative; Photoionization; Study; Heats

In this award, funded by the Experimental Physical Chemistry Program of the Division of Chemistry, Professor Tomas Baer of the University of North Carolina at Chapel Hill, together with his graduate, and undergraduate students, will investigate the thermochemistry of organometallic complexes in the gas phase using the technique of threshold photoelectron photoion coincidence (TPEPICO) mass spectrometry at Chapel Hill in concert with imaging photoelectron photoion coincidence (iPEPICO) measurements at the Swiss Light Source with Prof. Thomas Gerber. The project will also involve a collaboration with Prof. Bálint Sztáray and his students from Eötvös Loránd University (Budapest, Hungary).Organometallic species are important actors in a number of industrial chemical settings. An understanding of their bond energies, etc. is important to building up models of how these species react. The goal of work like that of Prof. Baer is to provide accurate and precise values of these bond energies.. In addition to the broader scientific impact of the proposed research work, Prof. Baer's students will receive significant exposure to some of the cutting-edge science being pursued in Europe -- training a new cadre of globally-engaged scientists in the United States.

在该奖项中，教堂山化学司的实验物理化学计划以及地下学生将使用阈值光电片段的热量阶段调查有机量化的热化学，并将使用阈值光光电摄影技术（TPEPICO）的质谱技术调查。与Ithotoelectron Hotoion合作（iPepepico）在瑞士光源中与托马斯·格伯（Thomas Gerber）教授。能量等对于贝尔教授提供的工作的目标很重要。在欧洲培训中，在美国，在欧洲培训中进行了杂技科学。