International Collaborative Photoionization Study of Heats of Formation and Bond Energies of Organometallic Complexes

有机金属配合物的生成热和键能的国际合作光电离研究

基本信息

批准号：
0743000
负责人：
Tomas Baer
金额：
$ 23.17万
依托单位：
University of North Carolina at Chapel Hill
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2008
资助国家：
美国
起止时间：
2008-07-15 至 2012-06-30
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=0743000&HistoricalAwards=false
关键词：
International Collaborative Photoionization Study Heats

项目摘要

In this award, funded by the Experimental Physical Chemistry Program of the Division of Chemistry, Professor Tomas Baer of the University of North Carolina at Chapel Hill, together with his graduate, and undergraduate students, will investigate the thermochemistry of organometallic complexes in the gas phase using the technique of threshold photoelectron photoion coincidence (TPEPICO) mass spectrometry at Chapel Hill in concert with imaging photoelectron photoion coincidence (iPEPICO) measurements at the Swiss Light Source with Prof. Thomas Gerber. The project will also involve a collaboration with Prof. Bálint Sztáray and his students from Eötvös Loránd University (Budapest, Hungary).Organometallic species are important actors in a number of industrial chemical settings. An understanding of their bond energies, etc. is important to building up models of how these species react. The goal of work like that of Prof. Baer is to provide accurate and precise values of these bond energies.. In addition to the broader scientific impact of the proposed research work, Prof. Baer's students will receive significant exposure to some of the cutting-edge science being pursued in Europe -- training a new cadre of globally-engaged scientists in the United States.

In this award, funded by the Experimental Physical Chemistry Program of the Division of Chemistry, Professor Tomas Baer of the University of North Carolina at Chapel Hill, together with his graduate, and undergraduate students, will investigate the thermochemistry of organic complexes in the gas phase using the technique of threshold photoelectron photoion coincidence (TPEPICO) mass spectrometry at Chapel Hill in concert with imaging photoelectron photoion coincidence （ipepico）用托马斯·格伯（Thomas Gerber）教授在瑞士光源的测量。该项目还将与BálintSztáray教授及其来自EötvösLoránd大学（匈牙利布达佩斯）的学生合作。在许多工业化学环境中，牛仔属物种是重要的参与者。对它们的键能等的理解对于建立这些物种的反应模型很重要。像贝尔教授这样的工作的目的是提供这些键能能量的准确和精确的价值。除了拟议的研究工作的更广泛的科学影响外，贝尔教授的学生还将获得欧洲一些尖端科学的大量曝光 - 培训一名新的全球范围内科学家。