Grain Size Stability and Consolidation of Nanostructured Particulates

纳米结构颗粒的粒度稳定性和固结

• 批准号: 0504286
• 负责人: Carl Koch
• 金额: --
• 依托单位: North Carolina State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-09-15 至 2009-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0504286&HistoricalAwards=false
• 关键词: Grain; Size; Stability; Consolidation; Nanostructured

TECHNICAL: Nanocrystalline materials have yet to realize their potential as engineering materials because of processing limitations. The challenge is to develop large-scale processing methods that can produce bulk nanostructured metals and alloys free of processing defects. The objective of the research is to develop strategies to stabilize nanoscale microstructures during consolidation of powder particulates at elevated temperatures. This is motivated by the fact that processing methods which can be scaled up for large volume production of nanoscale materials typically start out with powder particulates that must be consolidated into bulk form. These methods include mechanical attrition of powders that make large-size particulates with an internal nanocrystalline grain structure or chemical reactions that produce nanoscale powder particles. These methods have great versatility in producing a variety of alloy and multiphase systems. Their major drawback is the need to consolidate the powders into bulk form, attaining theoretical density and complete interparticle bonding, without significantly coarsening the nanoscale microstructure. The experimental approach to be used in this research emphasizes a systematic study of grain growth and the kinetic and thermodynamic factors that influence it in selected metals alloy prepared by mechanical attrition. Two model systems based on bcc Fe and fcc Ni will be selected for the research. Grain growth studies have shown fundamentally different behavior for nanocrystalline samples of these two metals, with the activation energies for grain growth being close to either lattice diffusion (Fe) or grain boundary diffusion (Ni). The possibility to stabilize nanocrystalline microstructures is explored by using alloy additions to reduce the grain boundary energy (thermodynamic basis) or limit the grain boundary mobility by pinning (kinetic basis). Equilibrium soluble and immiscible elements and second-phase oxide dispersion additives are added to the base metals to study the effectiveness of their ability to stabilize the microstructure. Guided by the grain growth studies, consolidation of powders will be carried out by sinter forging. The effectiveness of the consolidation processes is investigated using mechanical property tests suited to laboratory-scale sample sizes. The ductility and fracture surfaces should reveal the presence of processing defects. Analysis and simulation modeling is conducted to identify and optimize the thermodynamic and kinetic mechanisms that inhibit grain growth. NONTECHNICAL: The educational impact of the proposed research includes participation in the Kenan Fellows for Curriculum and Leadership Development program at North Carolina State University. A principal investigator acts as a mentor for a local K-12 teacher who serves a two-year fellowship in which he/she will carry out research and bring up-to-date knowledge of science, engineering, and technology into the classroom. Undergraduate students will share in research experience through participation in the REU program sponsored by the NSF.

技术：由于处理局限性，纳米晶体材料尚未意识到它们作为工程材料的潜力。面临的挑战是开发大规模加工方法，这些方法可以生产出无处理缺陷的散装纳米结构金属和合金。该研究的目的是制定稳定纳米级微观结构的策略，在升高温度下粉末颗粒的合并过程中。这是由于以下事实，即可以对大量生产的纳米级材料进行扩展的加工方法通常是从必须合并成大量形式的粉末颗粒开始的。这些方法包括机械磨损的粉末，这些粉末具有具有内部纳米晶体结构的大尺寸颗粒或产生纳米级粉末颗粒的化学反应。这些方法在生产各种合金和多相系统方面具有极大的多功能性。他们的主要缺点是需要将粉末整合到散装形式中，达到理论密度和完整的颗粒间键，而不会显着使纳米级微观结构变得明显。在这项研究中要使用的实验方法强调了对谷物生长的系统研究以及在机械损耗制备的选定金属合金中影响它的动力学和热力学因子。将选择基于BCC FE和FCC NI的两个模型系统进行研究。谷物生长研究表明，这两种金属的纳米晶样品的行为根本不同，晶粒生长的激活能接近晶格扩散（FE）或晶界扩散（NI）。通过使用合金添加来减少晶界能（热力学基础）或通过固定（动力学基础）限制晶界迁移率（动力学基础）来探索稳定纳米晶微观结构的可能性。将平衡可溶性和不混溶元素以及第二相氧化物分散添加剂添加到基础金属中，以研究其稳定微结构能力的有效性。在谷物生长研究的指导下，粉末将通过锻造进行巩固。使用适合实验室规模样本量的机械性能测试研究合并过程的有效性。延展性和断裂表面应揭示出处理缺陷的存在。进行分析和仿真模型以识别和优化抑制谷物生长的热力学和动力学机制。非技术性研究：拟议研究的教育影响包括参与北卡罗来纳州立大学的肯南研究员和领导力发展计划。一名首席研究员是当地K-12老师的导师，该老师是为期两年的奖学金，他/她将进行研究，并将科学，工程和技术的最新知识带入课堂。本科生将通过参加NSF赞助的REU计划分享研究经验。