US-Germany Cooperative Research: Synthesis of Hydrogen from Diesel Fuels

美德合作研究：柴油合成氢气

基本信息

批准号：
0339819
负责人：
Lanny Schmidt
金额：
--
依托单位：
University of Minnesota-Twin Cities
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2004
资助国家：
美国
起止时间：
2004-01-01 至 2007-06-30
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=0339819&HistoricalAwards=false
关键词：
US Germany Cooperative Research Synthesis

项目摘要

0339819SchmidtThis award supports Lanny Schmidt and students from the University of Minnesota-Twin Citiesin a collaboration with Olaf Deutschmann of the Institute of Chemical Engineering at the University of Karlruhe, Germany. The funding establishes a collaborative program for modeling the partial oxidation of diesel fuel and its components to produce hydrogen and light hydrocarbons for fuel cells and related applications. This program will build on past collaborations between the principal investigators on developing detailed models partial oxidation of methane. These will include mechanism development, simulations of experimental results, and predictions of process behavior. The models constructed will provide fundamental information on mechanisms of hydrocarbon reactions. There are currently no detailed models of hydrocarbon oxidation reactions, either homogeneous or on surfaces, which have been developed in sufficient detail for simulating fuel reforming to hydrogen. Development of these models will also have significant fundamental impact on interpreting experimental results and on theoretical bases for kinetic model development. Furthermore, the models will be crucial in developing technologies for fuel reforming for fuel cells because they require processing of complex mixtures of alkanes. Such models are essential in designing these important energy-producing technologies.

0339819Schmidt该奖项支持 Lanny Schmidt 和明尼苏达大学双城分校的学生与德国卡尔鲁厄大学化学工程研究所的 Olaf Deutschmann 合作。该资金建立了一个合作项目，对柴油及其成分的部分氧化进行建模，以生产用于燃料电池和相关应用的氢气和轻质烃。该计划将建立在主要研究人员过去合作开发甲烷部分氧化的详细模型的基础上。这些将包括机制开发、实验结果模拟和过程行为预测。构建的模型将提供有关碳氢化合物反应机制的基本信息。目前还没有碳氢化合物氧化反应的详细模型，无论是均质的还是表面的，这些模型都已经开发得足够详细以模拟燃料重整为氢气。这些模型的开发也将对实验结果的解释和动力学模型开发的理论基础产生重大的根本影响。此外，这些模型对于开发燃料电池燃料重整技术至关重要，因为它们需要处理复杂的烷烃混合物。这些模型对于设计这些重要的能源生产技术至关重要。