US-Germany Cooperative Research: Synthesis of Hydrogen from Diesel Fuels

美德合作研究：柴油合成氢气

基本信息

批准号：
0339819
负责人：
Lanny Schmidt
金额：
--
依托单位：
University of Minnesota-Twin Cities
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2004
资助国家：
美国
起止时间：
2004-01-01 至 2007-06-30
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=0339819&HistoricalAwards=false
关键词：
US Germany Cooperative Research Synthesis

项目摘要

0339819SchmidtThis award supports Lanny Schmidt and students from the University of Minnesota-Twin Citiesin a collaboration with Olaf Deutschmann of the Institute of Chemical Engineering at the University of Karlruhe, Germany. The funding establishes a collaborative program for modeling the partial oxidation of diesel fuel and its components to produce hydrogen and light hydrocarbons for fuel cells and related applications. This program will build on past collaborations between the principal investigators on developing detailed models partial oxidation of methane. These will include mechanism development, simulations of experimental results, and predictions of process behavior. The models constructed will provide fundamental information on mechanisms of hydrocarbon reactions. There are currently no detailed models of hydrocarbon oxidation reactions, either homogeneous or on surfaces, which have been developed in sufficient detail for simulating fuel reforming to hydrogen. Development of these models will also have significant fundamental impact on interpreting experimental results and on theoretical bases for kinetic model development. Furthermore, the models will be crucial in developing technologies for fuel reforming for fuel cells because they require processing of complex mixtures of alkanes. Such models are essential in designing these important energy-producing technologies.

0339819SCHMIDTITHIS奖支持Lanny Schmidt和来自明尼苏达大学 - 两国城市的学生与德国卡尔鲁厄大学化学工程研究所的Olaf Deutschmann合作。资金建立了一个协作计划，用于建模柴油燃料的部分氧化及其组件，以生产用于燃料电池和相关应用的氢和轻碳氢化合物。该计划将基于主要研究人员在开发甲烷的部分氧化方面的过去合作基础上。这些将包括机理发展，实验结果的模拟以及过程行为的预测。构建的模型将提供有关烃反应机制的基本信息。当前，尚无均质或表面上的烃氧化反应的详细模型，这些反应已足够详细地开发，以模拟燃料的燃料改革。这些模型的开发还将对解释实验结果和动力学模型开发的理论基础产生重大的基本影响。此外，这些模型对于开发用于燃料电池的燃料改革技术至关重要，因为它们需要处理复杂的烷烃混合物。这样的模型对于设计这些重要的能源生产技术至关重要。