Molecular Level Effects for Simple Electrode Reactions at Well Defined Polarizable Electrodes

明确的可极化电极上简单电极反应的分子水平效应

• 批准号: 0133758
• 负责人: W. Ronald Fawcett
• 金额: $ 42.16万
• 依托单位: University of California-Davis
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-02-01 至 2005-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0133758&HistoricalAwards=false
• 关键词: Molecular; Level; Effects; Simple; Electrode

Professor Ronald Fawcett of the University of California Davis is supported by the Analytical and Surface Chemistry Program to characterize the electrical double layer at single crystal gold microelectrode surfaces. Both novel experiments and theoretical studies will be performed. Aqueous and nonaqueous solvents will be investigated. Kinetic experiments will also be conducted at single crystal electrodes modified by a self-assembled monolayer. Monte Carlo calculations will be carried out to determine ion/electrode correlation functions in the diffuse boundary layer. This fundamental work underlies the understanding of electrochemical capacitors, synthesis, sensors, corrosion and the preparation of new materials.

加利福尼亚大学戴维斯大学的Ronald Fawcett教授得到了分析和表面化学计划的支持，以表征单晶金微电极表面的电气双层。新型实验和理论研究都将进行。 将研究水性和非水溶剂。 动力学实验还将在通过自组装单层修饰的单晶电极进行。 将执行蒙特卡洛计算以确定弥散边界层中的离子/电极相关函数。这项基本工作是理解电化学电容器，合成，传感器，腐蚀和制备新材料的基础。