Solution and Solid State Chemistry of Homo- and Hetero-Atomic Deltahedral Clusters of Main-Group Elements

主族元素同质和异质原子三角面体团簇的溶液和固态化学

• 批准号: 0098004
• 负责人: Slavi Sevov
• 金额: $ 30万
• 依托单位: University of Notre Dame
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2001
• 资助国家: 美国
• 起止时间: 2001-07-15 至 2005-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0098004&HistoricalAwards=false
• 关键词: Solution; Solid; State; Chemistry; Homo

The Advanced Materials Program in the Chemistry Division supports this award to University of Notre Dame to develop an understanding of redox potentials, oxidation states and reactivity of elements from Groups 12 to 15, and these groups include metallic, semimetallic or semi-conducting elements. The focus of the research will be solution and solid state chemistry based synthesis of homo- and hetero-atomic anion clusters, and to study the bonding of main group anion clusters based on germanium or Group III-V compounds. A number of neutral nanoparticles or semiconducting thin films will be synthesized, and reactions to produce polymeric materials with extended structures of linked clusters will be studied by Prof. Slavi Sevov with this award.With this award, negative oxidation states of elements from Groups 12 to 15 such as indium, bismuth, tin, gallium and other related elements will be studied with respect to their bonding, structures, coordination and reactivity of homo- and hetero-atomic anion clusters. Both solution chemistry and solid state chemistry will be followed to synthesize extended structures with linked clusters.

化学部门的先进材料计划支持巴黎圣母大学的奖项，以对12至15组的氧化还原电位，氧化状态和反应性有所了解，这些组包括金属，半金属或半导体元素。 这项研究的重点将是溶液和基于固态化学的均和异质原子阴离子簇的合成，并研究基于也或III-V组化合物的主要组阴离子簇的键合。 将合成许多中性纳米颗粒或半导体薄膜，并将通过该奖项来研究具有链接簇的延长结构的反应，并将其奖励研究。与该奖项相关。同性原子阴离子簇的反应性。 溶液化学和固态化学都将遵循与链接簇合成的扩展结构。