Infrared Spectroscopic Studies of the Structure and Reactions of Molecules on Metal Surfaces

金属表面分子结构和反应的红外光谱研究

• 批准号: 9616402
• 负责人: Michael Trenary
• 金额: $ 39万
• 依托单位: University of Illinois at Chicago
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1997
• 资助国家: 美国
• 起止时间: 1997-03-01 至 2001-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9616402&HistoricalAwards=false
• 关键词: Infrared; Spectroscopic; Studies; Structure; Reactions

Surface vibrational spectroscopy, using reflection absorption infrared methods, is the focus of this research project supported by the Analytical and Surface Chemistry Program. Professor Trenary and his students at the University of Illinois at Chicago will determine the identity and structure of adsorbed species using vibrational spectroscopy. Normal mode analysis will be applied to the interpretation of this spectroscopic data, enabling assignment of vibrational bands, and determination of structural parameters for the adsorbed species. The application of these methods to the methoxy intermediate on copper surfaces, and to isocyanide and related moieties on platinum surfaces are the primary systems of interest. The results of this work will see broad application in the routine use of surface IR to characterize reaction processes. The use of surface infrared spectroscopy as a routine analytical tool will be enabled by the development of normal mode analysis methods which are the subject of this research project. In order to understand reaction processes on surfaces, adsorbed reactants, products, and intermediates must be identified and structurally characterized. Normal mode methods will make this characterization routinely available to the surface chemistry community.

使用反射吸收红外方法的表面振动光谱是该研究项目的重点，该项目由分析和表面化学计划支持。 伊利诺伊大学芝加哥分校的特雷纳里教授和他的学生将利用振动光谱法确定吸附物质的身份和结构。 正则模式分析将应用于解释该光谱数据，从而能够分配振动带并确定吸附物质的结构参数。 这些方法对铜表面上的甲氧基中间体以及铂表面上的异氰化物和相关部分的应用是人们感兴趣的主要系统。 这项工作的结果将在表面红外表征反应过程的常规应用中得到广泛应用。 通过开发作为本研究项目主题的正态模式分析方法，将能够使用表面红外光谱作为常规分析工具。 为了了解表面的反应过程，必须识别吸附的反应物、产物和中间体并进行结构表征。 普通模式方法将使表面化学界可以常规地使用这种表征。