A new Iron Age! Making Iron complexes fit for C-C cross-coupling catalysis.

新的铁器时代！

• 批准号: DE230100978
• 负责人: Dr Marcus Korb
• 金额: $ 28.68万
• 依托单位: The University of Western Australia
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Early Career Researcher Award
• 财政年份: 2023
• 资助国家: 澳大利亚
• 起止时间: 2023-02-02 至 2026-02-01
• 项目状态: 未结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DE230100978
• 关键词: new; Iron; Age; Making; complexes

This project aims to develop new iron catalysts as alternatives to the expensive and increasingly rare noble metals currently used in C-C bond forming reactions, the most important single-step in the fine-chemicals sector. This project expects to create a flexible yet robust framework by introducing a hemilabile ligand into the backbone of the iron complex to control the number of vacant coordination sites. Expected outcomes of this project are 1) iron complexes able to catalyse biaryl couplings from sustainable substrates and 2) knowledge on structure-property relationships of iron-based catalytic processes. Australia will benefit by applying its own resources and help preserving the valuable noble metals for processes relying on them.

该项目旨在开发新型铁催化剂，作为目前用于 C-C 键形成反应（精细化学品领域最重要的一步）的昂贵且日益稀有的贵金属的替代品。 该项目期望通过将半不稳定配体引入铁配合物的主链来控制空配位点的数量，从而创建一个灵活而强大的框架。 该项目的预期成果是 1) 能够催化可持续底物联芳基偶联的铁络合物，2) 了解铁基催化过程的结构-性能关系。 澳大利亚将通过利用自己的资源而受益，并帮助保护贵金属用于依赖它们的工艺。