The interaction between polymer science and supramolecular chemistry has given rise to a diverse range of polymer supramolecular systems, which may possess rich supramolecular structures and thereby bring about special properties and functions. Many universities and research institutes in China have been engaged in the research of polymer supramolecular systems since the 1980s and have achieved a series of important innovative results in the research of polymer self-assembly, supramolecular polymerization and functional supramolecular systems, etc. Due to limited space, this review only selects and introduces several representative research examples, demonstrating how to develop and establish self-assembly methods starting from molecular design, combining structure construction with functional assembly, and constructing the ideas and achievements of a variety of polymer supramolecular systems.
高分子科学和超分子化学的相互作用产生了多种多样的聚合物超分子体系,其可能具有丰富的超分子结构,并由此带来特殊的性质与功能. 我国许多高校和科研院所自20世纪80年代开始从事聚合物超分子体系的研究,并在高分子自组装、超分子聚合以及功能超分子体系等研究方面取得了一系列重要创新成果. 由于篇幅有限,此综述只选择介绍了几个代表性的研究实例,展示了如何从分子设计出发,发展和建立自组装的方法,将结构构筑与功能组装结合,构建多种多样的聚合物超分子体系的思想和成果.