Poly(caprolactone)-based Plasticizers to reduce gas-check in PVC films

聚己内酯基增塑剂可减少 PVC 薄膜中的气体检查

• 批准号: 543853-2019
• 负责人: Maric, Milan
• 金额: $ 1.41万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Collaborative Research and Development Grants
• 财政年份: 2021
• 资助国家: 加拿大
• 起止时间: 2021-01-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=720800
• 关键词: Poly; caprolactone; based; Plasticizers; reduce

Plasticizers are used to increase the flexibility and workability of rigid polymers like poly(vinyl chloride) (PVC) for a myriad of commercial products such as wiring, cables, flooring and pool liners. For decades, di-2-ethylhexyl phthalate (DEHP; often termed dioctyl phthalate (DOP)) was the most common plasticizer used in PVC formulations. However, DEHP and its metabolites, particularly its monoester, have caused negative health effects, such as being an endocrine disruptor. Recently, DEHP was banned from use in children's toys and phthalate alternatives are rapidly being offered. We developed succinate-based esters that biodegrade to non-toxic metabolites after being discarded while also performing as well or better than DEHP in blend formulations. Further, we further optimized the process using green chemistry principles, using sustainable building blocks and reducing solvent, number of process steps and catalyst concentration. These green succinate ester plasticizers worked well as primary plasticizers for PVC. However, during our previous collaborations, we discovered that poly(caprolactone) (PCL) block co-oligomers were found to be very effective as secondary plasticizers, virtually eliminating gas-check, which is a phenomenon that limits production rates where air bubbles are entrained in the film when calendaring or roll-milling. The causes are not well described in literature. Our goal is to find the fundamental mechanism for gas-check reduction in PCL-block co-oligomer/PVC blends (due to either surface tension or rheological effects). In tandem with the industrial partner, we will determine the root causes for this effect and then design a suite of PCL-based secondary plasticizers tailored to various product lines. An economic evaluation of the derived PCL plasticizers will follow in preparation of scale-up. This project has potentially enormous industrial and socio-economic implications, as costly down-time is avoided while delivering another green plasticizer to market. The innovation from this CRD will create Canadian-based intellectual property, licensing opportunities and job creation due to being first on the market with such a product.

增塑剂用于提高聚氯乙烯 (PVC) 等硬质聚合物的柔韧性和可加工性，用于各种商业产品，例如电线、电缆、地板和泳池衬垫。 几十年来，邻苯二甲酸二-2-乙基己酯（DEHP；通常称为邻苯二甲酸二辛酯 (DOP)）是 PVC 配方中最常用的增塑剂。 然而，DEHP 及其代谢物，特别是其单酯，对健康造成了负面影响，例如成为内分泌干扰物。 最近，DEHP 被禁止在儿童玩具中使用，邻苯二甲酸盐替代品正在迅速出现。 我们开发了基于琥珀酸酯的酯，这些酯在废弃后可生物降解为无毒代谢物，同时在混合配方中的性能与 DEHP 一样好甚至更好。 此外，我们利用绿色化学原理、使用可持续构建模块和减少溶剂、工艺步骤数和催化剂浓度进一步优化了工艺。这些绿色琥珀酸酯增塑剂作为 PVC 的主增塑剂效果很好。 然而，在我们之前的合作中，我们发现聚己内酯 (PCL) 嵌段共聚低聚物作为辅助增塑剂非常有效，几乎消除了气体检查，这是一种限制夹带气泡的生产率的现象压延或辊磨时的薄膜中。 文献中没有很好地描述其原因。我们的目标是找到减少 PCL 嵌段共聚低聚物/PVC 共混物中气体检查的基本机制（由于表面张力或流变效应）。 我们将与工业合作伙伴合作，确定造成这种影响的根本原因，然后设计一套适合各种产品线的基于 PCL 的辅助增塑剂。 随后将对衍生的 PCL 增塑剂进行经济评估，以准备扩大规模。 该项目具有潜在的巨大工业和社会经济影响，因为在向市场提供另一种绿色增塑剂的同时避免了代价高昂的停机时间。 由于率先在市场上推出此类产品，该 CRD 的创新将为加拿大创造知识产权、许可机会和就业机会。