Repair and upgrade of the UV-Vis-NIR fluorometer with intergrating sphere and time-resolved capability

具有积分球和时间分辨能力的紫外-可见-近红外荧光计的维修和升级

• 批准号: RTI-2020-00702
• 负责人: Perepichka, Dmitrii
• 金额: $ 7.66万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Research Tools and Instruments
• 财政年份: 2019
• 资助国家: 加拿大
• 起止时间: 2019-01-01 至 2020-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=692895
• 关键词: Repair; upgrade; UV; Vis; NIR

We seek funding to urgently repair and upgrade the UV-Vis-near-IR spectrofluorometer acquired in 2014 with a prior NSERC-RTI grant, to continue and complete our on-going studies of advanced optoelectronic materials and devices. The two key features of the proposal are: (i) replacement of the integrating sphere that enables measurements of absolute luminescence quantum yield of solid samples and (ii) upgrade with a time-resolved spectroscopy module which enable life-time measurements and time-gated spectroscopy in the very broad ( nsec msec) temporal range. These features, combined with (already existing) near-infrared detector will make this instrument unique not only at McGill but also in the region. The instrument will become a departmental facility, used extensively by research groups of co-applicants and other members of McGill chemistry and Quebec Center for Advanced Materials (current users base comprises 11 academic groups). It will continuously contribute to training of 20+ students each year.******The capabilities enabled by this requested repair and upgrade are critical for continuing the research progress in several fields of fundamental scientific importance. Specifically, the instrument will be used to develop: a new class of organic room temperature phosphors, luminescent covalent organic frameworks, photo-actuating and up-converting materials with a spectrum of useful applications in the existing technologies (sensors, bioimaging, and renewable energy (photovoltaics)) as well as the development of new ones (eg, organic injection lasers). These are the key areas of strength of the co-applicants and major users. The training enabled by the instrument will contribute prominently to generalization' of our HQP who will become comfortable in materials design and synthesis, spectroscopy/photophysics and device engineering. These are the skills in demand by Canadian industry, considering its historic strength in photonics.**

我们寻求资金紧急修复和升级 2014 年获得的 NSERC-RTI 拨款购买的紫外-可见-近红外分光荧光计，以继续并完成我们正在进行的先进光电材料和器件的研究。该提案的两个关键特点是：（i）更换积分球，能够测量固体样品的绝对发光量子产率；（ii）升级时间分辨光谱模块，能够实现寿命测量和时间选通光谱在非常宽的时间范围内（纳秒毫秒）。这些功能与（现有的）近红外探测器相结合，将使该仪器不仅在麦吉尔而且在该地区独一无二。该仪器将成为一个院系设施，由麦吉尔化学和魁北克先进材料中心的共同申请人和其他成员组成的研究小组广泛使用（当前用户群包括 11 个学术团体）。每年它将持续为 20 多名学生的培训做出贡献。********所请求的修复和升级所带来的能力对于继续在几个具有基础科学重要性的领域取得研究进展至关重要。具体来说，该仪器将用于开发：新型有机室温荧光粉、发光共价有机框架、光驱动和上转换材料，在现有技术（传感器、生物成像和可再生能源）中具有一系列有用的应用（光伏））以及新产品（例如有机注入激光器）的开发。这些是共同申请人和主要用户的重点优势领域。该仪器提供的培训将对我们的 HQP 的推广做出重大贡献，他们将熟悉材料设计和合成、光谱/光物理和设备工程。考虑到加拿大在光子学方面的历史优势，这些是加拿大工业界所需要的技能。**