Development of Novel Cathode Materials (RexLa0.6-xSr0.4Co0.8Fe0.2O3) for Intermediate Temperature Solid Oxide Fuel Cells (Re=Rare earth element series

中温固体氧化物燃料电池新型正极材料（RexLa0.6-xSr0.4Co0.8Fe0.2O3）的开发（Re=稀土元素系列）

• 批准号: 2443518
• 金额: --
• 依托单位: University of Leeds
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2020
• 资助国家: 英国
• 起止时间: 2020 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2443518
• 关键词: Development; Novel; Cathode; Materials; RexLa0.6

Solid oxide fuel cells (SOFCs) can be considered as an alternative to traditional power generation sources such as coal, gas and biomass. In a SOFC, renewable fuel sources such as hydrogen is converted to electricity in a high to intermediate temperature solid-state electrochemical cell operating typically between 500 to 900 C. The fuel cell technology addresses an important issue of greenhouse gas emissions such as CO2 and CH4 which leads to global warming. SOFCs, in generating energy, could potentially meet not only the needs of the growing world population but would also be a cleaner, environmentally friendly source of energy. SOFC technology could address the future issue of the energy trilemma (energy security, sustainability and affordability) that the next generation could face if left unaddressed and neglected in the current times. SOFCs have the benefit of operating at a high efficiency of over 70%. Leeds research group has already developed new fast oxide-ion conducting solid electrolyte in a currently ongoing PhD research project. Since the porous Ni-based composite anode is well established, we intend to focus on the development of novel cathode materials to couple with the already developed solid electrolyte and established anode for the development of IT-SOFC operating between 600 - 800 C. The high surface area nanopowders of rare-earth (Re) co-doped LSCF (RexLa0.6-xSr0.4Co0.8Fe0.2O3) will be used for the development of a novel cathode. The development of cathode materials will be carried out systematically through RexLa0.6-xSr0.4Co0.8Fe0.2O3 nanopowders synthesis by the Leeds Alginate Process (LAP) originally developed by the research group at Leeds University in three previous PhD projects. This is an alginate mediated cation-exchange method developed by researchers at Leeds that has potential of yielding consistently high purity single phase complex oxide nanopowders with relative ease at low cost. A range of experimental techniques will be employed to determine the chemical, physical, thermal, magnetic, structural, catalytic, electrochemical and electrical properties of the high surface area nanopowders of Re-co-doped LSCF cathode materials by the alginate mediated ion-exchange process. The resulting cathode nanopowder and the cathode/electrolyte composite will then be pressed uniaxially to form discs and sintered at a range of different temperatures in order to study the chemical compatibility of materials in the selected temperature range. We will then evaluate the thermal, physical and chemical properties by differential scanning calorimetry, dilatometry and thermogravimetric analysis (DSC-TGA), Brunauer-Emmett-Teller (BET), X-ray fluorescence (XRF); magnetic and structural properties by X-ray Diffraction (XRD), High temperature-XRD, Scanning electron microscope, Transmission electron microscope and LaserRaman spectroscopy. Electrical properties will be evaluated by ac-impedance spectroscopy, half-cell manufacture by coating of solid electrolyte on porous cathode by spin coating or pulsed laser deposition (PLD), half-cell potentials by measuring open circuit potentials, area specific resistance of half-cell by ac-impedance spectroscopy. To consider the oxygen reduction capability of the cathode material, we will evaluate BET surface area of nanopowders, oxygen adsorption studies on nanopowders of cathode materials, oxygen reduction kinetics of cathode nanopowders by thermogravimetric analysis and mass spectroscopy (TGA-MS). Finally we will fabricate single cell SOFC and test it in the laboratory environment to assess the materials compatibility and power efficiency over the range of temperature of operation of an IT-SOFC for different compositions of the cathode material. This systematic study will enable us to identify and recommend a few of the compositions with optimum physico-chemical and electrochemical properties for further investigation.

固体氧化物燃料电池（SOFC）可被视为煤炭、天然气和生物质等传统发电来源的替代品。在 SOFC 中，氢等可再生燃料在通常在 500 至 900 C 之间运行的高温至中温固态电化学电池中转化为电能。燃料电池技术解决了二氧化碳和甲烷等温室气体排放的重要问题。这导致全球变暖。 SOFC 在发电方面不仅有可能满足不断增长的世界人口的需求，而且也将成为一种更清洁、环境友好的能源。 SOFC 技术可以解决未来能源三难问题（能源安全、可持续性和可负担性），如果在当前时代不加以解决和忽视，下一代人可能会面临这一问题。 SOFC 的优点是运行效率高达 70% 以上。利兹研究小组已经在目前正在进行的博士研究项目中开发出新型快速氧化物离子导电固体电解质。由于多孔镍基复合阳极已经成熟，我们打算重点开发新型阴极材料，与已经开发的固体电解质和成熟的阳极相结合，用于开发在 600 - 800 C 之间运行的 IT-SOFC。稀土 (Re) 共掺杂 LSCF (RexLa0.6-xSr0.4Co0.8Fe0.2O3) 的表面积纳米粉末将用于开发新型阴极。正极材料的开发将通过利兹藻酸盐工艺（LAP）合成RexLa0.6-xSr0.4Co0.8Fe0.2O3纳米粉末来系统地进行，该工艺最初由利兹大学研究小组在之前的三个博士项目中开发。这是利兹研究人员开发的一种藻酸盐介导的阳离子交换方法，有潜力以相对容易的方式以低成本生产一致高纯度的单相复合氧化物纳米粉末。将采用一系列实验技术，通过藻酸盐介导的离子交换过程，确定 Re 共掺杂 LSCF 阴极材料的高表面积纳米粉末的化学、物理、热、磁、结构、催化、电化学和电性能。然后将所得的阴极纳米粉末和阴极/电解质复合材料单轴压制形成圆盘，并在不同温度范围内烧结，以研究材料在选定温度范围内的化学相容性。然后，我们将通过差示扫描量热法、膨胀法和热重分析（DSC-TGA）、Brunauer-Emmett-Teller（BET）、X射线荧光（XRF）来评估热、物理和化学性质；通过 X 射线衍射 (XRD)、高温 XRD、扫描电子显微镜、透射电子显微镜和激光拉曼光谱分析磁性和结构特性。电气特性将通过交流阻抗谱进行评估，通过旋涂或脉冲激光沉积（PLD）在多孔阴极上涂覆固体电解质来制造半电池，通过测量开路电位来评估半电池电位，半电池的面积比电阻通过交流阻抗谱分析细胞。为了考虑正极材料的氧还原能力，我们将评估纳米粉末的BET表面积、正极材料纳米粉末的氧吸附研究、通过热重分析和质谱（TGA-MS）评估正极纳米粉末的氧还原动力学。最后，我们将制造单电池 SOFC 并在实验室环境中对其进行测试，以评估不同阴极材料成分的 IT-SOFC 在工作温度范围内的材料兼容性和功率效率。这项系统研究将使我们能够识别并推荐一些具有最佳物理化学和电化学特性的组合物，以供进一步研究。