Kinetic Study on Superior Performance of Silica-Coated Cathode Catalysts for PEFC

PEFC用二氧化硅包覆正极催化剂优异性能的动力学研究

• 批准号: 23360350
• 负责人: KISHIDA Masahiro
• 金额: $ 3.16万
• 依托单位: Kyushu University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011-11-18 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23360350/
• 关键词: 固体高分子形燃料電池; カソード電極触媒; シリカ被覆; 耐久性向上; 物質移動; 速度解析; 反応工学・プロセスシステム

We have reported that supported Pt catalysts covered with silica layer showed extremely high durability for the cathode in PEFC, but the layer might limit reaction rate due to slow mass transfer within the silica layer. In this work we studied on the mass transfer in silica layer and on the reason for the superior durability of the coated catalyst. The structure of silica layer was successfully controlled by changing coating condition. The silica layer prepared using methyltriethoxysilane has larger pore size and exhibited both the high activity and high durability. The reason why the coating catalysts show high durability could not be revealed, but the interaction between metal surface and silica layer, or positive charge of silica layer might suppress the dissolution of Pt species during reaction. Finally, it was also found that the coated Pd-Co catalysts showed extremely high durability for the cathode in PEFC, as compared with uncoated catalysts.

我们报道说，用二氧化硅覆盖的支持的PT催化剂显示出PEFC中阴极的耐用性极高，但是由于二氧化硅层内的质量转移缓慢，该层可能限制了反应速率。在这项工作中，我们研究了二氧化硅层中的传质，以及涂层催化剂的耐用性的原因。 二氧化硅层的结构通过改变涂层条件成功控制。使用甲基氧基硅烷制备的二氧化硅层具有较大的孔径，并且表现出高活性和高耐用性。 涂层催化剂表现出高耐用性的原因无法揭示，但是金属表面和二氧化硅层之间的相互作用或二氧化硅层的正电荷可能会抑制反应过程中PT物种的溶解。 最后，与未涂层的催化剂相比，涂层的PD-CO催化剂在PEFC中显示出极高的耐用性。

项目成果

Entrapment of cobalt(II) tetraphenylporphyrin aggregates in silica nanocapsule

二氧化硅纳米胶囊中四苯基卟啉钴 (II) 聚集体的包埋

• 发表时间: 2012
• 作者: Kyoso Masuda;Hideki Matsune;Sakae Takenaka;Masahiro Kishida;Masahiro Kishida
• 通讯作者: Masahiro Kishida

Synthesis of Silica-Coated AgCl Nanoparticles in Aqueous Poly(vinylpyrrolidone) Solution

聚(乙烯基吡咯烷酮)水溶液中二氧化硅包覆的AgCl纳米粒子的合成

• DOI: 10.1246/bcsj.20130327
• 发表时间: 2014
• 期刊: Bulletin of the Chemical Society of Japan
• 影响因子: 4
• 作者: Kyoso Masuda;Hideki Matsune;Sakae Takenaka;Masahiro Kishida
• 通讯作者: Masahiro Kishida