Mechanical-Alloying-Assisted Syntheses of Cobalt-Containing Multi-Component Systems and MAX Phases

含钴多组分系统和 MAX 相的机械合金化辅助合成

• 批准号: 538050-2018
• 负责人: Liu, RongR
• 金额: $ 2.91万
• 依托单位: Carleton University
• 依托单位国家: 加拿大
• 项目类别: Collaborative Research and Development Grants
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=759490
• 关键词: Mechanical; Alloying; Assisted; Syntheses; Cobalt

Mechanical alloying (MA) is a materials-processing method that involves the repeated welding, fracturing, and rewelding of a mixture of powder particles, generally in a high energy ball mill, to produce a controlled, very fine microstructure, which results in high performance of the final material. MA-assisted-synthesis is characterized by a combination of mechanical alloying the mixed powder to very fine structure and then sintering. In this research two categories of material will be synthesized utilizing the MA technique. The first is cobalt-containing multi-component system (MCS), which is designed based on the combined concept of cobalt-based superalloy and high-entropy alloy (HEA). The former is also known as Stellite alloy, displaying exceptional properties such as high temperature strength, corrosion, oxidation, wear and erosion resistance, due to the unique chemical composition. The latter is composed of at least five elements in equiatomic or near equiatomic composition, exhibiting various excellent properties such as high hardness, good ductility and high temperature stability, by introduction of extra entropy to stabilize the structure. Different from traditional HEAs, the proposed cobalt-containing MCS alloys still have Co as the major element alloying with Cr, W, Mo, Ni, Mn, etc., but Co content will be reduced compared to Stellite alloys, thus lowering the cost of the alloys. MAX phases are layered ternary carbides and nitrides, making property combination of metallic and ceramic materials, which are popularly employed in extreme environments. In this research, MAX phases, including Cr2AlC, Ti3SiC2, Ti3AlC2, Ti2AlC, and Ti2AlN, potentially for nuclear applications, will also be synthesized with MA to improve their performance by creating very fine grained microstructures. The MA mixed powders will be solidified via special sintering processes such as spark plasma sintering and laser cladding, which enable to produce very fine grained microstructures due to rapid heating and cooling. It is expected that these novel materials synthesized by the advanced process possess superior performance to the existing materials from conventional methods, becoming emerging advanced materials for various industrial applications.

机械合金化 (MA) 是一种材料加工方法，涉及粉末颗粒混合物的重复焊接、断裂和再焊接（通常在高能球磨机中），以产生受控的非常精细的微观结构，从而产生高性能最终材料。 MA辅助合成的特点是将混合粉末机械合金化至非常精细的结构，然后烧结。在本研究中，将利用 MA 技术合成两类材料。第一个是含钴多元体系（MCS），它是基于钴基高温合金和高熵合金（HEA）的组合概念而设计的。前者又称司太立合金，由于其独特的化学成分，表现出高温强度、耐腐蚀、抗氧化、耐磨和耐冲蚀等优异性能。后者由至少五种等原子或近等原子组成的元素组成，通过引入额外的熵来稳定结构，表现出高硬度、良好的延展性和高温稳定性等多种优异性能。与传统HEA不同，所提出的含钴MCS合金仍然以Co为主要元素与Cr、W、Mo、Ni、Mn等合金化，但与Stellite合金相比Co含量会降低，从而降低了成本合金。 MAX相是层状三元碳化物和氮化物，结合了金属和陶瓷材料的性能，广泛应用于极端环境。在这项研究中，MAX 相，包括 Cr2AlC、Ti3SiC2、Ti3AlC2、Ti2AlC 和 Ti2AlN（可能用于核应用）也将与 MA 一起合成，通过创建非常细晶粒的微观结构来提高其性能。 MA混合粉末将通过特殊的烧结工艺（例如放电等离子烧结和激光熔覆）进行固化，由于快速加热和冷却，能够产生非常细晶粒的微观结构。预计这些通过先进工艺合成的新型材料具有优于传统方法现有材料的性能，成为各种工业应用的新兴先进材料。