Research and Development of Novel Conducting Materials Consisting of Carbon Skeletons Based on a Molecular Engineering Approach

基于分子工程方法的碳骨架新型导电材料的研究与开发

• 批准号: 59430015
• 负责人: YAMABE Tokio
• 金额: $ 13.25万
• 依托单位: Kyoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (A)
• 财政年份: 1984
• 资助国家: 日本
• 起止时间: 1984 至 1985
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-59430015/
• 关键词: Synthetic Metals; Conductive Polymers; Organic Semiconductors; Low-Dimensional Conductive Materials; 導電機構

Summary of this project is as follows.1. Theoretical analysis of spin-specific vibronic coupling and discussion in association with Cooper Pair.2. Calculations of the electronic structures of miscellaneous conductive polymers including novel polymers.3. Theoretical analysis of interchain conduction mechanism in lightly-doped polyacetylene.4. Experimental and theoretical analyses of polythiophene and poly(3-methylthiophene).5. Experimental analyses of electric transport properties of the pristine and the doped polyacenic materials prepared by pyrolytic treatment of phenol-formaldehyde resin.

本项目的概要如下： 1．自旋特异性振动耦合的理论分析及与库珀对的讨论。2．包括新型聚合物在内的各种导电聚合物的电子结构计算。 3．轻掺杂聚乙炔链间传导机理的理论分析。 4．聚噻吩和聚(3-甲基噻吩)的实验和理论分析。5．酚醛树脂热解处理制备的原始和掺杂多并苯材料的电传输性能实验分析。

项目成果

J.Chem.Phys.82-12. (1985)

J.Chem.Phys.82-12。

Solid State Commun.51-12. (1984)

固态通讯51-12。

Synth.Metals. 11-2. (1985)

合成金属。

Phys. Rev. B. 32-10. (1985)

物理。

Chem. Phys. Letters. 112-3. (1984)

化学。