The preparation of semiconductor nanoparticles by PLA in water and the their evaluation as functional materials

PLA在水中制备半导体纳米粒子及其功能材料评价

• 批准号: 17560592
• 负责人: TANAKA Katsumi
• 金额: $ 2.24万
• 依托单位: The University of Electro-Communications
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2006
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17560592/
• 关键词: Titania nanoparticles; Pulsed Laser Ablation; PLA in Water; ICP-Mass; Visible Light Response; Environmental Cleaning; Quantum Size Effect; Thin Film; パルスレーザーアプレーション; 微粒子半導体; 酸化チタン; シリコン微粒子; 光触媒; 半導体微粒子; 可視光応答触媒

The amount of titanium formed by TiO2 single crystal PLA in water was measured by ICP-mass spectrometry. The PLA yield was evaluated as a function of laser fluence, water thickness, pH and temperature in solution, and acid kind. The yield was mainly controlled by the former two factors and was shown by two equations. The size and behavior of titania particles on the substrate were studied with STM. The size of the particles as small as 4nm was detected and they easily moved on the substrate surface by biased voltage between tip and nano-particles. The bandgap of the thin films was measured to be 3.87 to 4.13eV with diffused reflectance spectroscopy. Such clear bandgap enlargement due to quantum-size effect is quite unique only on these nano-particles. Such blue shift is disadvantage for the photo-catalytic reaction on TiO2. However, the thin films were photo-active to methylene blue degradation not only with ultraviolet but also with >400nm visible light. The fact was interpreted by the impurity levels formed in between the enlarged bandgap such as nitrogen involved by PTA in water. Probably high concentration of impurity in nanoparticles play significant role on producing much holes active for photo-oxidation with visible light.

通过ICP-质谱法测量TiO2单晶PLA在水中形成的钛的量。 PLA 产率作为激光能量密度、水厚度、溶液 pH 值和温度以及酸种类的函数进行评估。收率主要受前两个因素控制，并由两个方程表示。使用 STM 研究了基底上二氧化钛颗粒的尺寸和行为。检测到的颗粒尺寸小至 4nm，并且通过尖端和纳米颗粒之间的偏置电压，它们很容易在基板表面上移动。通过漫反射光谱测量薄膜的带隙为3.87至4.13eV。由于量子尺寸效应而导致的这种明显的带隙扩大仅在这些纳米颗粒上是非常独特的。这种蓝移对于 TiO2 上的光催化反应是不利的。然而，薄膜不仅在紫外线下而且在>400nm可见光下都具有光活性，可导致亚甲基蓝降解。这一事实可以通过扩大带隙之间形成的杂质水平来解释，例如水中 PTA 涉及的氮。纳米颗粒中的高浓度杂质可能在产生大量对可见光光氧化具有活性的空穴方面发挥着重要作用。

项目成果

Deposition of Potassium-oxygen on Silicon Surfaces by Pulsed Laser Ablation of Potassium Superoxide : Study of Work Function Changes

通过脉冲激光烧蚀超氧化钾在硅表面沉积钾氧：功函数变化的研究

• 发表时间: 2006
• 期刊: Surface Science Vol 600
• 作者: C.-K.Choo;D.Suzawa;K.Tanaka
• 通讯作者: K.Tanaka

Time-Resolved Photoluminescence Spectra of Si Species Encapsulated in Zeolite Supercages

封装在沸石超级笼中的硅物质的时间分辨光致发光光谱

• 发表时间: 2005
• 期刊: Journal of Physical Chemistry B 109
• 作者: K.Tanaka;Y.Komatsu;C-K Choo
• 通讯作者: C-K Choo

水中レーザアブレーション法で作製したチタニア微粒子によるメチレンブルー光分解反応

水下激光烧蚀法制备二氧化钛细颗粒的亚甲基蓝光解反应

• 发表时间: 2005
• 作者: 高尾誠;チュウチャオキョン;田中勝己
• 通讯作者: 田中勝己

Deposition of Pottasium-oxygen on Silicon Surfaces by Pulsed Laser Ablation of Pottasium Superoxide : Study of Work Function Changes

通过脉冲激光烧蚀超氧化钾在硅表面沉积钾氧：功函数变化的研究

• 发表时间: 2006
• 期刊: Surface Science 600
• 作者: C.K.Choo;D.Suzawa;K.Tanaka
• 通讯作者: K.Tanaka

酸化チタン薄膜の製造方法及び酸化チタン薄膜を有する樹脂製品

氧化钛薄膜的制造方法及具有氧化钛薄膜的树脂制品

• 发表时间: 2007