Analysis of surface electronic structure by STM with resonance excitation

共振激发下 STM 分析表面电子结构

• 批准号: 13440099
• 负责人: NISHITANI Ryusuke
• 金额: $ 8.51万
• 依托单位: Kyushu Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2001
• 资助国家: 日本
• 起止时间: 2001 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-13440099/
• 关键词: STM; Local density of states; Tunneling Spectroscopy; Tunneling induced light emission; alkanethiol molecules; organic thin films; spectrally resolved light intensity image; 共鳴励起状態; マイクロクラスター; 有機分子

(1)Development of apparatus for simultaneous measurements of STM. STS and STM light emission spectra.The experimental system of Scanning Probe Microscopy for STM, STS and STM light, emission measurements has been developed. The light emitted from STM is collected by using lens installed in STM head. These three kinds of measurements can be made simultaneously by communicating between STM controller and optical detecting system, which enables us the comparison among topographic image by STM, local density of states by STS and optical spectra by STM-induced light emission.(2)Comparison of light emission spectra with local density of states.We have measured STM-induced light emission from organic molecules adsorbed Au(111) surface at low temperatures of about 77K. The emission spectra have been measured at the same time of STS and STM measurements for octanedithiol films on Au(111) surfaces, and the optical spectra been correlated with topographic images by STM and local density of states by STS. These data have been compared with those for the clean Au(111) surface's.The change of optical spectra due to molecule adsorption has been observed in peak position and spectral shape in the longer wavelength side, of emission peak for' clean Au(111) surface : These change can be explained by the change in local density of states due to octanedithiol adsorption on Au (111) : the decrease in density of states at the energy near Fermi level and the increase above 0.3eV with respect to Fermi level. This comparison has been made successfully for the first time based on the simultaneous measurements by our experimental system

(1)STM同步测量装置的研制。 STS和STM光发射光谱。研制了STM、STS和STM光发射测量的扫描探针显微镜实验系统。 STM 发出的光通过安装在 STM 头中的透镜收集。通过STM控制器和光学检测系统之间的通信，可以同时进行这三种测量，这使得我们能够对STM的形貌图像、STS的局域态密度和STM诱导光发射的光谱进行比较。(2)比较我们测量了在约 77K 的低温下吸附 Au(111) 表面的有机分子的 STM 诱导光发射。在Au(111)表面上的辛二硫醇薄膜的STS和STM测量的同时测量了发射光谱，并且将光谱与STM的形貌图像和STS的局域态密度相关联。这些数据已与干净的 Au(111) 表面的数据进行了比较。在“干净的 Au(111)”的发射峰的较长波长侧的峰值位置和光谱形状中，观察到了由于分子吸附而引起的光谱变化。表面：这些变化可以通过由于辛二硫醇吸附在 Au (111) 上而引起的局域态密度的变化来解释：在费米能级附近能量态密度降低，而相对于费米能级高于 0.3eV 时态密度增加 等级。基于我们的实验系统的同步测量，首次成功进行了这种比较

项目成果

R.Czajka: "STM and STS investigations of transition metals' clusters (Cr,CoCr,Ni) produced by the plasma gas condensation (PGC) source"Colloids and Surfaces A : Physico-chemical and Engineering Aspects. 202. 195-206 (2002)

R.Czajka：“等离子气体冷凝 (PGC) 源产生的过渡金属簇 (Cr、CoCr、Ni) 的 STM 和 STS 研究”胶体和表面 A：物理化学和工程方面。

Ryusuke Nishitani: "Circular polarization dependent mapping of STM induced light from magnetic metal particles"APIP Conference Series. 3. 142-146 (2001)

Ryusuke Nishitani：“来自磁性金属颗粒的 STM 感应光的圆偏振相关映射”APIP 会议系列。

R.Czajka: "Variable Temperature STM/AFM invesigations of Transition Metals' Clusters (Cr, CoCr, Ni) Produced by PGC source"APIP Conference Series. 3. 137-141 (2001)

R.Czajka：“PGC 源生产的过渡金属簇（Cr、CoCr、Ni）的变温 STM/AFM 研究”APIP 会议系列。

Ryusuke Nishitani: "A study of Alkanethiol Film on Au by STM-induced Luminescence"Surface Review and Letters. (in press). (2003)

Ryusuke Nishitani：“通过 STM 诱导发光对 Au 上的链烷硫醇薄膜进行研究”表面评论和快报。

R.Nishitani: "STM-induced luminescence spectra from A(111) with STM tips of Pt-Ir alloys"AIP Conference Proceedings 696, 12th International Conference on Scanning Tunneling Microscopy/Spectroscopy and Related Techniques. 696. 927-933 (2003)

R.Nishitani：“A(111) 与 Pt-Ir 合金 STM 尖端的 STM 诱导发光光谱”AIP 会议论文集 696，第 12 届扫描隧道显微镜/光谱学及相关技术国际会议。