Development of the concentration and separation system for multi-compornents by ion-pair phase separation phenomena with fluorosurfactant

利用含氟表面活性剂离子对相分离现象开发多组分浓缩分离系统

基本信息

  • 批准号:
    05805068
  • 负责人:
  • 金额:
    $ 1.34万
  • 依托单位:
  • 依托单位国家:
    日本
  • 项目类别:
    Grant-in-Aid for General Scientific Research (C)
  • 财政年份:
    1993
  • 资助国家:
    日本
  • 起止时间:
    1993 至 1994
  • 项目状态:
    已结题

项目摘要

New two types of three-phase separation phenomena were found by the charge neutralization of perfluorooctanate ion ; they are amine type in the neutral pH to alkaline solution and that of polar organic solvent in the acidic solution.In this study, the concentration and separation of several kinds of metal-chelate and physiological active substrates have been discussed in detail based on fundamental findings obtained from these phase separation phenomena.In the amine type (e.g.the case in the presence of n-amylamine), threephase separation phenomenon was confirmed in the pH range of 7 to 8.Each phases were successively water phase and two kinds of water-immisible phase (second phase and first phase) from upper side.The homogeneous liquid-liquid extraction method using these phenomena was applied to three components such as L-ascorbic acid, hemogrobin and alpha, beta, gamma, delta-tetrakis (4-trimethylaminophenyl) porphine (TTMAPP) assuming that separate the medical substances in human b … More lood.As the results, they were able to be separated into water (L-ascorbic acid), second (hemoglobin) and first (TTMAPP) phases, respectively using only a one-step process with addition of amylamine to the perfluorooctanoic acid solution.On the other hand, in the polar organic solvent type (e.g.the case in the presence of dimethylsulfoxide), the three-phase separation phenomenon was confirmed in the pH range of 0.42 to 0.46.This extraction method was applied to eight kinds of synthetic water-soluble porphyrin.As the results, three kinds of water-soluble porphyrin was quantitatively extracted and separated in water phase, second phase and first phase, respectively.The structure and physico-chemical property of these solutes is an important as a model when this extraction method is applied to the separation for other solutes.In conclusion, above-described valuable results for the development of new separation method "multi-compornents homogeneous liquid-liquid extraction"was obtained during the past two years.In the near future, the discovery of novel multi-phase separation phenomenon and the application to the extensive sample containing useful solute would be aggressively done. Less
通过全氟离子的电荷中和发现了两种新型的三相分离现象。它们是酸性溶液中中性pH的胺类型。在这项研究中,已经根据从这些相分离现象中获得的基本发现进行了详细讨论,在这项研究中,已经详细讨论了几种金属氯酸盐和物理活性底物的浓度和分离。 7 to 8.Each phases were successfully water phase and two kinds of water-immisible phase (second phase and first phase) from upper side.The homogeneous liquid-liquid extraction method using these phenomena was applied to three components such as L-ascorbic acid, hemogrobin and alpha, beta, gamma, delta-tetrakis (4-trimethylaminophenyl) porphine (TTMAPP) assuming that separate人类B中的医疗物质……大声。结果,它们能够分为水(L-抗甲酸),第二(血红蛋白)和第一个(TTMAPP)阶段,分别仅使用一个步骤的过程,并将淀粉胺添加到全氟辛基酸溶液中。在0.42至0.46的pH范围内证实了三相分离现象。将这种提取方法应用于八种合成水溶性卟啉。结果,在水相和第一阶段的结构中,将三种水溶性卟啉定量地萃取并分离,当时是求解的,当时是求解的,这些特性是在这些阶段,这些特性是这些溶解性的,这些方法是这些特性的,这些方法是这些溶解性的,这些方法是这些溶解性的,这些卟啉是这些特性的。结论,在过去的两年中,获得了新的分离方法“多型液体液 - 液体提取”的新分离方法的上述有价值的结果。在不久的将来,发现新颖的多相分离现象以及对包含有用的有用的有用的实用性的实用性。较少的

项目成果

期刊论文数量(12)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Shukuro IGARASHI: "A Novel Homogeneous Liquid-Liquid Extraction Based on Three-Phase Formation With Perfluorosurfactant and Amine Compounds" Chemistry Letters. 1189-1190 (1994)
Shukuro IGARASHI:“基于全氟表面活性剂和胺化合物三相形成的新型均质液液萃取”化学快报。
  • DOI:
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    0
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Go YOKOHASHI: "A pH-Dependent Three-Phase Separation Phenomenon with Perfluorooctanoic Acid/Dimetylsulfoxide/Water System" Journal of Colloid and Interface Science. (印刷中). (1995)
Go YOKOHASHI:“全氟辛酸/二甲基亚砜/水系统的 pH 依赖性三相分离现象”胶体与界面科学杂志(1995 年)。
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  • 影响因子:
    0
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Go YOKOHASHI: "A pH-Dependent Three-Phase Separation Phenomenon with Perfluorooctanoic Acid/DMSO/Water System" Journal of Colloid and Interface Science. (印刷中). (1995)
Go YOKOHASHI:“全氟辛酸/DMSO/水系统的 pH 依赖性三相分离现象”《胶体与界面科学》杂志(1995 年出版)。
  • DOI:
  • 发表时间:
  • 期刊:
  • 影响因子:
    0
  • 作者:
  • 通讯作者:
Go YOKOHASHI: "A pH-Dependent Three-Phase Separation Phenomenon with Perfluorooctanoic Acid/Dimethylsulfoxide/Water System" Journal of Colloid and Interface Science. (1995)
Go YOKOHASHI:“全氟辛酸/二甲基亚砜/水系统的 pH 依赖性三相分离现象”胶体与界面科学杂志。
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    0
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IGARASHI Shukuro其他文献

IGARASHI Shukuro的其他文献

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{{ truncateString('IGARASHI Shukuro', 18)}}的其他基金

Creation of new time measurement-chemiluminescent reaction and prototyping of compact analyzer
新型时间测量化学发光反应的创建和紧凑型分析仪的原型设计
  • 批准号:
    25620103
  • 财政年份:
    2013
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Challenging Exploratory Research
Study on the progressive analysis of environmental water by the development of high speed・high powerful concentration and separation system
开发高速·强力浓缩分离系统,对环境水进行连续分析的研究
  • 批准号:
    14550777
  • 财政年份:
    2002
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Development of total "down sizing" analytical system following high-speed and high-powered concentration method
遵循高速、高性能浓缩法开发整体“小型化”分析系统
  • 批准号:
    11555224
  • 财政年份:
    1999
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Scientific Research (B).
Development of ultra trace sensing method of vital substances based on new chemical amplification
基于新型化学放大的生命物质超痕量传感方法开发
  • 批准号:
    10450315
  • 财政年份:
    1998
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Scientific Research (B)
Development of homogeneous liquid-liquid extraction method and its application to high performance separation-detection system
均相液液萃取方法的研制及其在高性能分离检测系统中的应用
  • 批准号:
    08650959
  • 财政年份:
    1996
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
Development of Porphyrin chelate for NMR imaging diagnosis agent
核磁共振成像诊断剂卟啉螯合物的研制
  • 批准号:
    05555225
  • 财政年份:
    1993
  • 资助金额:
    $ 1.34万
  • 项目类别:
    Grant-in-Aid for Developmental Scientific Research (B)
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