In-Situ Ion Beam Measurement of Electrodeposition Reaction

电镀反应的原位离子束测量

• 批准号: 03453075
• 负责人: ITO Yasuhiko
• 金额: $ 3.39万
• 依托单位: KYOTO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for General Scientific Research (B)
• 财政年份: 1991
• 资助国家: 日本
• 起止时间: 1991 至 1993
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-03453075/
• 关键词: Ion Beam; Electro-Deposition; Ni-Co Alloy; In-Situ Measurement; Proton Beam; Radiation Spectrum; プロントビーム; 溶融塩; イオンビ-ム; NiーCo合金; InーSitu測定; プロトンビ-ム; Van de Graaff型加速器

The feasibility of In-Situ PIXE spectroscopy for electrodeposition reaction analysis has been demonstrated, by showing the experimental results of electrodeposition of copper, iron and nickel-cabalt alloy, as well as those of anodic dissolution of copper and iron, as examples.This was achieved by the following three major successful results :(1)Thin film electrode suitable for ion beam irradiation has been prepared by sputtering technique, which is composed of organic membrance, chromium oxide film and copper film.(2)Electrolytic cell with the above thin film electrode at one side of the walls and with an electolyte circulating system has been constructed, by which In-Situ ion beam irradiation under constant electrolytic condition could be achieved through the experiment.(3)Differential pumping system in the beam line has developed.

The feasibility of In-Situ PIXE spectroscopy for electrodeposition reaction analysis has been demonstrated, by showing the experimental results of electrodeposition of copper, iron and nickel-cabalt alloy, as well as those of anodic dissolution of copper and iron, as examples.This was achieved by the following three major successful results :(1)Thin film electrode suitable for ion beam irradiation has been prepared by sputtering technique, which is composed of （2）有机膜，氧化物膜和铜膜。（2）构建了带有上述薄膜电极在墙壁的一侧和电解质循环系统的电解细胞，可以通过实验来实现恒定电解条件下在恒定电解条件下的坐骨离子束照射。

项目成果

森谷 公一,吉田 紘二,伊藤 靖彦: "NiーCoの合金電析のInーSitu測定" 電気化学および工業物理化学.

Koichi Moriya、Koji Yoshida、Yasuhiko Ito：“镍钴合金沉积的原位测量”电化学和工业物理化学。

森谷 公一,鎌田 正裕,伊藤 靖彦: "ラジオトレ-サ-法による鉄の電気化学反応に関する研究" 電気化学および工業物理化学. 60. (1992)

Koichi Moriya、Masahiro Kamata、Yasuhiko Ito：“用放射性示踪剂方法研究铁的电化学反应”电化学和工业物理化学 60。（1992）。

Y.Ito,T.Shimada,and H.Kawamura: "Electrochemical Formation of Thin Carbon Film from Molten Chloride System" Proc.8th International Symposium on Molten Salts. 574-585 (1992)

Y.Ito、T.Shimada 和 H.Kawamura：“从熔融氯化物体系中电化学形成薄碳膜”Proc.第八届国际熔盐研讨会。

H.Moriyama, T.Nagae, K.Moritani and Y.Ito: "A Comparison of Production of Irradiation Defects in Lithium Ceramics" Fusion Technology. 1434-1438 (1993)

H.Moriyama、T.Nagae、K.Moritani 和 Y.Ito：“锂陶瓷中辐照缺陷产生的比较”聚变技术。

H.Moriyama, T.Nagae, K.Moritani and Y.Ito: "A Comparison of Production Behavior of Irradiation Defects in Lithium Ceramics" Fusion Technology. 1434-1438 (1993)

H.Moriyama、T.Nagae、K.Moritani 和 Y.Ito：“锂陶瓷中辐照缺陷的生产行为比较”聚变技术。