Electrochemiluminescence of organic molecules in water using the bipolar electrolytic micelle disruption method

使用双极电解胶束破坏法对水中有机分子进行电化学发光

• 批准号: 22K14708
• 负责人: ビラニ エレナ
• 金额: $ 3万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Early-Career Scientists
• 财政年份: 2022
• 资助国家: 日本
• 起止时间: 2022-04-01 至 2024-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-22K14708/
• 关键词: Electrochemiluminescence; Bipolar Electrochemistry; Organic Molecules; Micelles; Electric Fields; Electrochemiluminescence; Bipolar Electrochemistry; Organic Molecules; Micelles; Electric Fields

The aim of the proposed research plan is to develop a bipolar electrochemical method for the generation of electrochemiluminescence (ECL) from organic molecules in aqueous solution. The method relies on the use of micelles generated by a redox-active surfactant where the organic molecule is entrapped and dissolved in water.At present, the micelle disruption method has been implemented to form a film of an organic molecule, such as 9,10-diphenylanthracene (DPA), on the electrode and, after addition of a coreactant like tri-n-propylamine (TPrA), ECL emission has been detected and the light intensity is correlated with the thickness of the film formed on the electrode.

拟议的研究计划的目的是开发一种双极电化学方法，用于从水溶液中有机分子产生电化学发光（ECL）。 The method relies on the use of micelles generated by a redox-active surfactant where the organic molecule is entrapped and dissolved in water.At present, the micelle disruption method has been implemented to form a film of an organic molecule, such as 9,10-diphenylanthracene (DPA), on the electrode and, after addition of a coreactant like tri-n-propylamine (TPrA),已经检测到ECL发射，并且光强度与电极上形成的膜的厚度相关。