Investigations of ionic liquid - solute systems by surface sensitive spectroscopic techniques - part of the initiative "Shaping micro- and macroscopic properties of ionic liquid-solute systems"

通过表面敏感光谱技术研究离子液体-溶质系统 - “塑造离子液体-溶质系统的微观和宏观特性”计划的一部分

• 批准号: 29200579
• 负责人: Professor Dr. Harald Morgner
• 金额: --
• 依托单位: School of Chemistry, Physics and Earth Sciences
• 依托单位国家: 德国
• 项目类别: Priority Programmes
• 财政年份: 2006
• 资助国家: 德国
• 起止时间: 2005-12-31 至 2011-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/29200579?language=en
• 关键词: Investigations; ionic; liquid; solute; systems; Investigations; ionic; liquid; solute; systems

We propose to investigate experimentally the molecular structure of the surface of ionic liquids with surface sensitive methods. The goals are to determine thermodynamic properties of ionic liquids by determining their surface structure and to validate the results of simulations. We are able to determine directly concentration depth profiles of liquid surfaces with the method neutral impact collision ion scattering spectroscopy (NICISS). The concentration depth profiles yield the surface excess of the different species. Knowing the surface tension and making use of the Gibbs equation the chemical potentials can be determined. The chemical potential is an information in general required for optimizing chemical processes. An important prerequisite for the investigations is the control of the cleanliness of the liquid surfaces. Surface sensitive methods are especially suitable for detecting the presence of surface active impurities. Measuring the surface tension of the investigated substances we will be able to gain data of systems with controlled cleanliness of the surface. Even though our project will be of general benefit for the entire priority program, it will be carried out in close cooperation between 4 groups. The project is an essential contribution for a further understanding of ionic liquid structure-property relationships in its own right, the four research groups will mutually benefit from participating in an interdisciplinary network of chemical engineers, physicists, and chemists. New methods of generating physico-chemical data are validated with existing methodology, and the large set of data obtained from ionic liquids of known purity is shared within the network, thus enabling the partners to dissect the results from a cross-section of science: fundamental and theoretical as well as technological and experimental.

我们建议使用表面敏感方法的实验研究离子液体表面的分子结构。目标是通过确定其表面结构并验证模拟结果来确定其热力学特性。我们能够使用方法中性冲击碰撞离子散射光谱（NICISS）来确定液体表面的直接浓度深度谱。浓度深度轮廓产生不同物种的表面过度。知道表面张力并使用Gi​​bbs方程，可以确定化学电位。化学潜力通常是优化化学过程所需的信息。调查的一个重要先决条件是控制液体表面的清洁度。表面敏感的方法特别适合检测表面活性杂质的存在。测量所研究物质的表面张力，我们将能够获得具有控制表面清洁度的系统数据。即使我们的项目将对整个优先级计划带来一般利益，但它将在4组之间密切合​​作进行。该项目是进一步理解离子液体结构特性关系本身的重要贡献，这四个研究小组将从参与化学工程师，物理学家和化学家的跨学科网络中互惠互利。通过现有方法来验证生成物理化学数据的新方法，并且从已知纯度的离子液体中获得的大量数据在网络中共享，从而使伙伴能够从科学的横截面：基本和理论，理论以及技术和实验中剖析结果。