CAREER: Harnessing Mineralogy and Polymer Science to Elucidate Mechanisms and Mitigation Strategies for Mineral Scaling in Membrane Desalination

职业：利用矿物学和聚合物科学阐明膜淡化中矿物结垢的机制和缓解策略

• 批准号: 2145627
• 负责人: Tiezheng Tong
• 金额: $ 51.92万
• 依托单位: Colorado State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2022
• 资助国家: 美国
• 起止时间: 2022-07-01 至 2027-06-30
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2145627&HistoricalAwards=false
• 关键词: CAREER; Harnessing; Mineralogy; Polymer; Science

Membrane-based technologies such as reverse osmosis (RO) are increasingly being utilized to provide clean water in the United States and worldwide under a rapidly changing climate and growing water scarcity. Currently, RO is the best available commercial technology for extracting and recovering clean water from a wide range of impaired water sources including seawater, inland brackish water, and municipal/industrial wastewater. However, the formation and precipitation of inorganic scales at the surface of RO membranes severely limit their water recovery and adversely impact the overall process efficiency and cost of water produced by RO desalination and water reuse plants. Compared to organic/biological membrane fouling, the mechanisms of formation and precipitation of inorganic scales at RO membrane surfaces are poorly understood as they involve complex chemical reactions and nucleation phenomena at polymer-mineral-water interfaces. The overarching goal of this CAREER project is to advance the fundamental understanding of mineral scaling at the surface of RO membranes. The successful completion of this project will benefit society through the development of new fundamental knowledge to advance the development and implementation of more efficient and cost-effective solutions to control and mitigate mineral scaling in RO desalination and water reuse systems. Further benefits to society will be achieved through student education and training including the mentoring of a graduate student and an undergraduate student at Colorado State University.Membrane scaling remains an important and unresolved challenge that limits the water recovery and overall system efficiency of commercial reverse osmosis (RO) desalination and water reuse plants. There are still critical knowledge gaps in the fundamental understanding of RO membrane scaling. First, the key physical/chemical processes and factors that control the extent of mineral scaling in RO membranes are not well understood. Second, the utilization of surface modification to mitigate mineral scaling in RO membranes has met with only limited success. Third, there is a lack of fundamental knowledge and principles to guide the design of antiscalants to mitigate the formation and precipitation of amorphous silica scales in RO membranes. This CAREER proposal will address these critical knowledge gaps. The guiding hypothesis of the proposed research is that polymers used as RO membrane surface modifiers or antiscalants can control the extent of mineral scaling by altering the thermodynamics and kinetics of scale nucleation events at membrane-water interfaces and the subsequent attachments of nascent mineral scales to membrane surfaces. Two key goals of the research are to: (1) Characterize and unravel the roles of scale nucleation thermodynamics, kinetics, and mineral-membrane affinity on the extent of RO membrane scaling and (2) Develop structure-property-performance relationships to guide and inform the design of scaling-resistant RO membranes and polymeric antiscalants to minimize and prevent RO membrane scaling. The successful completion of this project has the potential for transformative impact through the generation of new fundamental knowledge to advance the development of more effective strategies to control and mitigate membrane scaling in RO desalination and water reuse plants. To implement the educational and training goals of this CAREER project, the Principal Investigator (PI) will work with the Native American STEM Institute of Colorado State University (CSU) to develop and implement lectures and hands-on experiments for Native American high school students to learn about the critical science and engineering of challenges around water sustainability including the desalination of seawater and brackish water. In addition, the PI plans to partner with the ENpower Bridge program of CSU’s Engineering College to encourage and recruit students from underrepresented groups to pursue undergraduate/graduate education in Environmental Engineering.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在快速变化的气候和日益严重的水资源短缺的情况下，反渗透 (RO) 等基于膜的技术越来越多地被用于在美国和世界范围内提供清洁水，目前，反渗透是提取和回收清洁水的最佳可用商业技术。然而，反渗透膜表面无机垢的形成和沉淀严重限制了其水回收，并对水产生不利影响。与有机/生物膜污染相比，RO 海水淡化和水回用厂生产的水的整体工艺效率和成本，人们对 RO 膜表面无机垢的形成和沉淀机制知之甚少，因为它们涉及复杂的化学反应和成核现象。该职业项目的总体目标是增进对反渗透膜表面矿物结垢的基本了解，该项目的成功完成将通过开发新的基础知识来造福社会。开发和实施更先进、更具成本效益的解决方案，以控制和减轻反渗透海水淡化和水回用系统中的有效矿物结垢，将通过学生教育和培训（包括对研究生和本科生的指导）实现进一步的社会效益。膜结垢仍然是一个重要且尚未解决的挑战，限制了商业反渗透 (RO) 海水淡化和水回用工厂的水回收和整体系统效率。对 RO 膜结垢的基本理解仍然存在关键的知识差距。首先，控制反渗透膜中矿物质结垢程度的关键物理/化学过程和因素尚不清楚；其次，利用表面改性来减轻反渗透膜中的矿物质结垢仅取得有限的成功。缺乏指导阻垢剂设计以减轻反渗透膜中无定形二氧化硅垢的形成和沉淀的基础知识和原则。本职业提案将解决这些关键知识差距。该研究的指导假设是聚合物用作反渗透膜。膜表面改性剂或阻垢剂可以通过改变膜-水界面处水垢成核事件的热力学和动力学以及随后新生矿物垢在膜表面的附着来控制矿物结垢的程度，该研究的两个关键目标是：（1）表征并揭示结垢成核热力学、动力学和矿物膜亲和力对 RO 膜结垢程度的作用，以及 (2) 建立结构-性能-性能关系指导和指导抗结垢反渗透膜和聚合物阻垢剂的设计，以最大限度地减少和防止反渗透膜结垢。该项目的成功完成有可能通过产生新的基础知识来推动更有效策略的开发，从而产生变革性影响。控制和减轻 RO 海水淡化和水回用厂中的膜结垢 为了实现该职业项目的教育和培训目标，首席研究员 (PI) 将与科罗拉多州立大学 (CSU) 的美国原住民 STEM 研究所合作开发和开发。实施讲座以及为美国原住民高中生进行实践实验，以了解水可持续性挑战的关键科学和工程，包括海水和咸水淡化。此外，PI 计划与科罗拉多州立大学工程学院的 ENpower Bridge 项目合作。鼓励和招收代表性不足群体的学生攻读环境工程本科/研究生教育。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Which Surface Is More Scaling Resistant? A Closer Look at Nucleation Theories for Heterogeneous Gypsum Nucleation in Aqueous Solutions

哪种表面更耐结垢？

• DOI: 10.1021/acs.est.2c06560
• 发表时间: 2022-11
• 期刊: Environmental Science & Technology
• 影响因子: 11.4
• 作者: Yin, Yiming;Li, Tianshu;Zuo, Kuichang;Liu, Xitong;Lin, Shihong;Yao, Yiqun;Tong, Tiezheng
• 通讯作者: Tong, Tiezheng