Controlling the Interaction Between Carbon Dioxide and Cementitious Materials Using Biomimetic Molecules

使用仿生分子控制二氧化碳和胶凝材料之间的相互作用

• 批准号: 2028462
• 负责人: Warda Ashraf
• 金额: $ 49.2万
• 依托单位: University of Texas at Arlington
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-12-15 至 2024-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2028462&HistoricalAwards=false
• 关键词: Controlling; Interaction; Between; Carbon; Dioxide

This research aims to make sustainable infrastructure materials, including supplementary cementitious materials (SCMs) and alkali-activated materials (AAM), last longer by reducing their deterioration when these are exposed to carbon dioxide. This research will further contribute to the low-carbon future by advancing the understanding and applications of cementitious materials that can directly serve as carbon dioxide sinks. The outreach effort of this research involves developing a multidisciplinary workforce with faculty members and students from civil engineering, materials science, and chemistry to address the challenges of creating sustainable and durable materials for civil infrastructures. The direct educational benefits include mentored research opportunities for undergraduate and high school students as well as underrepresented groups. These opportunities will provide students with exposure to advanced research facilities and motivate them to pursue higher education in the field of infrastructure materials. This research will capitalize on the biomimetic approaches of engineering the growth, aggregation, and characteristics of in-situ precipitated calcium carbonate particles to control the interaction between cementitious materials and carbon dioxide. The specific objectives include: (i) determining the effectiveness of in-situ precipitated metastable calcium carbonate (mCaCO3) and calcium carbonate-organic hybrid (mCOH) phases to avoid degradation of calcium silicate hydrate (C-S-H) and calcium aluminum silicate hydrate (C-A-S-H) gel phases when exposed to external carbon dioxide, thus enhancing the carbonation resistance of cementitious composites containing AAMs and SCMs; (ii) investigating how biomimetic molecules can be used to precipitate specific mCaCO3 with controlled morphologies and properties in carbonation cured matrices so that their in-situ formations can be leveraged to develop high-performance cementitious matrices; (iii) investigating the functional relationship between biomimetic molecules and the polymorphic crystallization of calcium carbonate particles, and therefore, developing non-natural and affordable biomimetic molecules that can be used as chemical admixtures in cementitious materials.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

这项研究旨在通过减少暴露于二氧化碳时的劣化，使可持续基础设施材料（包括辅助胶凝材料（SCM）和碱活化材料（AAM））的使用寿命更长。这项研究将通过增进对可直接用作二氧化碳汇的水泥材料的理解和应用，进一步为低碳未来做出贡献。这项研究的外展工作涉及培养一支由土木工程、材料科学和化学领域的教员和学生组成的多学科队伍，以应对为土木基础设施创造可持续和耐用材料的挑战。直接的教育效益包括为本科生和高中生以及代表性不足的群体提供指导研究机会。这些机会将为学生提供接触先进研究设施的机会，并激励他们在基础设施材料领域接受高等教育。这项研究将利用仿生方法对原位沉淀碳酸钙颗粒的生长、聚集和特性进行工程设计，以控制胶凝材料和二氧化碳之间的相互作用。具体目标包括： (i) 确定原位沉淀亚稳态碳酸钙 (mCaCO3) 和碳酸钙有机杂化 (mCOH) 相的有效性，以避免硅酸钙水合物 (C-S-H) 和硅酸钙铝水合物 (C-A-S-H) 降解当暴露于外部二氧化碳时形成凝胶相，从而增强含有 AAM 和 SCM 的水泥基复合材料的抗碳化性； (ii) 研究如何使用仿生分子在碳酸化固化基质中沉淀出具有受控形态和性质的特定 mCaCO3，以便利用其原位形成来开发高性能水泥基体； (iii) 研究仿生分子与碳酸钙颗粒多晶型结晶之间的功能关系，从而开发非天然且经济实惠的仿生分子，可用作水泥材料中的化学外加剂。该奖项反映了 NSF 的法定使命，并已被通过使用基金会的智力优点和更广泛的影响审查标准进行评估，认为值得支持。

项目成果

Effects of magnesia in semi-hydraulic and non-hydraulic calcium silicate binders during carbonation curing

半水硬和非水硬硅酸钙粘结剂碳化养护过程中氧化镁的影响

• DOI: 10.1016/j.conbuildmat.2022.127628
• 发表时间: 2022-07
• 期刊: Construction and Building Materials
• 影响因子: 7.4
• 作者: Khan, Rakibul I.;Siddique, Salman;Ashraf, Warda
• 通讯作者: Ashraf, Warda

Amino acids as performance-controlling additives in carbonation-activated cementitious materials

氨基酸作为碳酸化活化水泥材料中的性能控制添加剂

• DOI: 10.1016/j.cemconres.2021.106501
• 发表时间: 2021-09-01
• 期刊: Cement and Concrete Research
• 影响因子: 11.4
• 作者: Rakibul I. Khan;W. Ashraf;J. Olek
• 通讯作者: J. Olek

Carbon sequestration in graphene oxide modified cementitious system

氧化石墨烯改性胶凝体系中的碳封存

• DOI: 10.1016/j.jobe.2022.105356
• 发表时间: 2022-10-01
• 期刊: Journal of Building Engineering
• 影响因子: 6.4
• 作者: G. Mishra;Ashraf Warda;Surendra P. Shah
• 通讯作者: Surendra P. Shah

A comparative investigation on the effects of nanocellulose from bacteria and plant-based sources for cementitious composites

细菌纳米纤维素和植物源纳米纤维素对水泥基复合材料影响的比较研究

• DOI: 10.1016/j.cemconcomp.2021.104316
• 发表时间: 2022-01
• 期刊: Cement and Concrete Composites
• 影响因子: 10.5
• 作者: Haque, Muhammad Intesarul;Ashraf, Warda;Khan, Rakibul I.;Shah, Surendra
• 通讯作者: Shah, Surendra

Role of biopolymers in enhancing multiscale characteristics of carbonation-cured cementitious composites

生物聚合物在增强碳化固化水泥基复合材料多尺度特性中的作用

• DOI: 10.1016/j.cemconcomp.2022.104766
• 发表时间: 2022-09-01
• 期刊: Cement and Concrete Composites
• 影响因子: 10.5
• 作者: Rakibul I. Khan;Muhammad Intesarul Haque;W. Ashraf;Surendra P. Shah;Navid Saleh
• 通讯作者: Navid Saleh