PFI-TT: Electrochemically Reactive Membrane Filtration for Enhanced Recalcitrant Pollutant Removal

PFI-TT：电化学反应膜过滤增强顽固污染物去除能力

• 批准号: 2016472
• 负责人: Wen Zhang
• 金额: $ 25万
• 依托单位: New Jersey Institute of Technology
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-09-01 至 2023-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2016472&HistoricalAwards=false
• 关键词: PFI; TT; Electrochemically; Reactive; Membrane

The broader impact/commercial potential of this Partnerships for Innovation-Technology Translation (PFI-TT) project is to promote industrialization and commercialization of innovative electrified or electrochemically reactive membrane filtration systems for water treatment and pollutant degradation. Decentralized or point-of-use water and wastewater treatment facilities (e.g., landfill leachate, surface and groundwater remediation, and hospital discharge) could benefit from this membrane process to eradicate potentially hazardous water pollutants, improve downstream treatability or degradation efficiency, and lower environmental and health risks from the exposure or discharge of water pollutants such as industrial solvents or additives. The research outcome will provide information for the rational design of electrochemical membrane systems that exhibit new features of both pollutant degradation and fouling mitigation. The project may pave the way toward a new generation of reactive membrane filtration development. Moreover, valuable research experiences and commercialization training will be offered to postdoctoral fellows and students to become technology innovators and business leaders in membrane technologies. Under-represented and minority students will be recruited through the Garden State Louis Stokes Alliance for Minority Participation (GS-LSAMP) program as well as student organizations or chapters.The proposed project will provide a new fundamental insight into electrochemical degradation for emerging water micropollutants on membrane filtration platforms in an effort to transform traditionally passive filtration processes to chemically reactive systems. The project will explore novel electrical polarizations to induce pulsed surface electrochemical reactions to improve reaction efficiencies and longevity of the electrode membranes. The project will explore membrane synthesis, characterization, and filtration experiments to promote the fundamental science and engineering principles of electrochemical membranes. The specific goals are to (1) devise novel electrochemical applications of porous electrode membranes to empower pollutant rejection, degradation and fouling mitigation; (2) delineate the chemical stability and longevity changes of the electrode membrane under various electrochemical reactions; (3) demonstrate potential new membrane fouling mechanisms (e.g., dielectrophoresis); and (4) understand new degradation pathways of highly refractory micropollutants such as poly- and perfluoroalkyl substances (PFASs).This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该创新技术转化合作伙伴关系 (PFI-TT) 项目更广泛的影响/商业潜力是促进用于水处理和污染物降解的创新电气化或电化学反应膜过滤系统的工业化和商业化。分散式或使用点水和废水处理设施（例如，垃圾填埋场渗滤液、地表水和地下水修复以及医院排放物）可以受益于这种膜工艺，以消除潜在有害的水污染物，提高下游可处理性或降解效率，并降低环境污染暴露或排放工业溶剂或添加剂等水污染物带来的健康风险。该研究成果将为电化学膜系统的合理设计提供信息，该系统表现出污染物降解和污染缓解的新特征。该项目可能为新一代反应性膜过滤的发展铺平道路。此外，还将为博士后和学生提供宝贵的研究经验和商业化培训，使其成为膜技术的技术创新者和商业领袖。代表性不足的少数族裔学生将通过花园州路易斯斯托克斯少数族裔参与联盟 (GS-LSAMP) 计划以及学生组织或分会招募。拟议的项目将为新兴水微污染物的电化学降解提供新的基本见解膜过滤平台致力于将传统的被动过滤过程转变为化学反应系统。该项目将探索新型电极化来引发脉冲表面电化学反应，从而提高电极膜的反应效率和寿命。 该项目将探索膜合成、表征和过滤实验，以促进电化学膜的基础科学和工程原理。具体目标是（1）设计多孔电极膜的新型电化学应用，以增强污染物截留、降解和污染缓解能力； (2)描绘电极膜在各种电化学反应下的化学稳定性和寿命变化； (3) 展示潜在的新膜污染机制（例如介电泳）； (4) 了解高难微污染物（如多氟烷基物质和全氟烷基物质 (PFAS)）的新降解途径。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Elucidating facet dependent electronic and electrochemical properties of Cu2O nanocrystals using AFM/SCEM and DFT

使用 AFM/SCEM 和 DFT 阐明 Cu2O 纳米晶体的晶面依赖性电子和电化学特性

• DOI: 10.1016/j.nantod.2022.101538
• 发表时间: 2022-08
• 期刊: Nano Today
• 影响因子: 17.4
• 作者: Ma, Qingquan;Young, Joshua;Basuray, Sagnik;Cheng, Guangming;Gao, Jianan;Yao, Nan;Zhang, Wen
• 通讯作者: Zhang, Wen

Electrochemical Aging and Halogen Oxides Formation on Multiwalled Carbon Nanotubes and Fe 3 O 4 @g-C 3 N 4 Coated Conductive Membranes

多壁碳纳米管和 Fe 3 O 4 @g-C 3 N 4 涂层导电膜的电化学老化和卤素氧化物的形成

• DOI: 10.1021/acs.iecr.2c02847
• 发表时间: 2022-09
• 期刊: Industrial & Engineering Chemistry Research
• 影响因子: 4.2
• 作者: Ma, Qingquan;Gao, Jianan;Potts, Courtney;Tong, Xiao;Tao, Yi;Zhang, Wen
• 通讯作者: Zhang, Wen

Decoupling Electron‐ and Phase‐Transfer Processes to Enhance Electrochemical Nitrate‐to‐Ammonia Conversion by Blending Hydrophobic PTFE Nanoparticles within the Electrocatalyst Layer

通过在电催化剂层中混合疏水性 PTFE 纳米颗粒，解耦电子和相转移过程，以增强电化学硝酸盐到氨的转化

• DOI: 10.1002/aenm.202203891
• 发表时间: 2023-01-15
• 期刊: Advanced Energy Materials
• 影响因子: 27.8
• 作者: Jianan Gao;Qingquan Ma;Joshua Young;J. Crittenden;Wen Zhang
• 通讯作者: Wen Zhang