Collaborative Research: Chemically Modified, Plasma-Nanoengineered Graphene Nanopetals for Spontaneous, Self-Powered and Efficient Oil Contamination Remediation

合作研究：化学改性、等离子体纳米工程石墨烯纳米花瓣用于自发、自供电和高效的石油污染修复

• 批准号: 1949910
• 负责人: Tengfei Luo
• 金额: $ 20万
• 依托单位: University of Notre Dame
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2020
• 资助国家: 美国
• 起止时间: 2020-06-01 至 2024-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1949910&HistoricalAwards=false
• 关键词: Collaborative; Research; Chemically; Modified; Plasma

Spills and leakage of oil during offshore oil production or marine transportation cause both long-term damage to water ecosystems and loss of valuable resources. Thus, efficient strategies for capturing and treating such releases are urgently required. Gravity-driven siphons allow the transport of liquids between phases. Siphons have been utilized for various applications and hold promise for oil recovery. However, siphon devices generally suffer from significant issues such as low oil removal flow rate, poor stability, and inability to self-restart after disruption of the siphon. The goal of this project is to develop a novel oil skimming technology based on a new chemically modified graphene material. The hydrophobic nature of graphene is expected to result in high remediation efficiency. Experiments guided by computational molecular simulations will provide fundamental understanding of the interaction of oil with graphene nanochannels. Successful completion of this research will help guide the design of spontaneous, self-powered, and continuous oil remediation systems with significantly enhanced efficiency. Such systems would have broad-reaching impact on society by alleviating environmental and human health impacts of spilled oil. The overall goal of this research project is to understand the nature of interaction between oil and graphene nanochannels. This will be achieved through experiments designed to elucidate the mechanisms governing the synergistic effects of the nanochannel geometry and surface functionalization of plasma-nanoengineered, vertically standing graphene petal (GP) oil skimmers. Guided by molecular simulation results, researchers will design and demonstrate an oil skimmer system based on chemically modified GPs with controlled morphologies for spontaneous, self-powered, and highly efficient oil spill remediation. The knowledge learned from this research will offer insights into developing unique graphene materials to address pressing oil pollution issues. The design principles will also accelerate broader applications of graphene materials to other environmental applications such as seawater desalination, wastewater treatment, and soil and air pollution prevention and remediation. The project will also include significant educational activities, including research programs for local K-12 students, teachers, and undergraduates. Society will benefit from students acquiring relevant knowledge and skills to diversify and train the STEM workforce of the future.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

海上石油生产或海上运输过程中的石油溢出和泄漏不仅会对水生态系统造成长期破坏，还会造成宝贵资源的损失。因此，迫切需要有效的策略来捕获和处理此类释放。重力驱动的虹吸管允许液体在相之间输送。虹吸管已用于各种应用，并有望用于石油回收。然而，虹吸装置普遍存在除油流量低、稳定性差、虹吸中断后无法自启动等重大问题。该项目的目标是开发一种基于新型化学改性石墨烯材料的新型撇油技术。石墨烯的疏水性预计将带来高修复效率。由计算分子模拟指导的实验将为油与石墨烯纳米通道的相互作用提供基本的了解。这项研究的成功完成将有助于指导自发、自供电、连续的石油修复系统的设计，并显着提高效率。此类系统将通过减轻溢油对环境和人类健康的影响，对社会产生广泛影响。该研究项目的总体目标是了解油和石墨烯纳米通道之间相互作用的本质。这将通过旨在阐明等离子体纳米工程垂直石墨烯花瓣（GP）撇油器的纳米通道几何形状和表面功能化的协同效应的机制的实验来实现。在分子模拟结果的指导下，研究人员将设计并演示一种基于化学改性的 GP 的撇油器系统，其具有受控的形态，可用于自发、自供电和高效的溢油修复。从这项研究中学到的知识将为开发独特的石墨烯材料以解决紧迫的石油污染问题提供见解。该设计原理还将加速石墨烯材料在海水淡化、废水处理、土壤和空气污染预防和修复等其他环境应用中的更广泛应用。该项目还将包括重要的教育活动，包括针对当地 K-12 学生、教师和本科生的研究项目。社会将受益于学生获得相关知识和技能，以多样化和培训未来的 STEM 劳动力。该奖项反映了 NSF 的法定使命，并通过使用基金会的智力价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Simultaneous solar-driven seawater desalination and continuous oil recovery

同步太阳能驱动海水淡化和连续采油

• DOI: 10.1016/j.nanoen.2022.108160
• 发表时间: 2023-03
• 期刊: Nano Energy
• 影响因子: 17.6
• 作者: Wu, Shiwen;Jian, Ruda;Tian, Siyu;Zhou, Long;Luo, Tengfei;Xiong, Guoping
• 通讯作者: Xiong, Guoping

Molecular understanding of the effect of hydrogen on graphene growth by plasma-enhanced chemical vapor deposition

通过等离子体增强化学气相沉积对氢对石墨烯生长影响的分子理解

• DOI: 10.1039/d1cp04510e
• 发表时间: 2022-05
• 期刊: Physical Chemistry Chemical Physics
• 影响因子: 3.3
• 作者: Wu, Shiwen;Huang, Dezhao;Yu, Haoliang;Tian, Siyu;Malik, Arif;Luo, Tengfei;Xiong, Guoping
• 通讯作者: Xiong, Guoping

Bio-inspired salt-fouling resistant graphene evaporators for solar desalination of hypersaline brines

用于超咸水太阳能淡化的仿生防盐垢石墨烯蒸发器

• DOI: 10.1016/j.desal.2022.116197
• 发表时间: 2023-01
• 期刊: Desalination
• 影响因子: 9.9
• 作者: Wu, Shiwen;Tian, Siyu;Jian, Ruda;Zhou, Long;Luo, Tengfei;Xiong, Guoping
• 通讯作者: Xiong, Guoping

Anisotropically tuning interfacial thermal conductance between graphite and poly(ethylene oxide) by lithium-ion intercalation: A molecular dynamics study

通过锂离子嵌入各向异性调节石墨和聚环氧乙烷之间的界面热导：分子动力学研究

• DOI: 10.1016/j.ijheatmasstransfer.2022.123134
• 发表时间: 2022-10
• 期刊: International Journal of Heat and Mass Transfer
• 影响因子: 5.2
• 作者: Tian, Siyu;Xu, Zhihao;Wu, Shiwen;Luo, Tengfei;Xiong, Guoping
• 通讯作者: Xiong, Guoping

A self-assembled nanoporous polyelectrolytic interlayer for highly stable zinc metal anodes

用于高度稳定的锌金属阳极的自组装纳米多孔聚电解中间层

• DOI: 10.1016/j.cej.2023.142276
• 发表时间: 2023-04
• 期刊: Chemical Engineering Journal
• 影响因子: 15.1
• 作者: Tian, Siyu;Zhou, Long;He, Wei;Tian, Yafen;Zhou, Yue;Wu, Shiwen;Jian, Ruda;Balkus, Kenneth J.;Luo, Tengfei;Xiong, Guoping
• 通讯作者: Xiong, Guoping