SusChEM: Collaborative Research: Theoretical and Experimental Investigation of Iron Oxysulfide for Terawatt Photovoltaics

SusChEM：合作研究：太瓦光伏发电中氧硫化铁的理论与实验研究

• 批准号: 1306291
• 负责人: Qiming Zhang
• 金额: $ 18.85万
• 依托单位: University of Texas at Arlington
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-08-01 至 2017-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1306291&HistoricalAwards=false
• 关键词: SusChEM; Collaborative; Research; Theoretical; Experimental

Technical Description: The objective of this project is to synthesize and investigate iron oxysulfide, in particular sulfurized hematite, with the goal of replacing critical components in the current solar cell technologies for next-generation photovoltaics. Sulfurized hematite, with an appropriate concentration of sulfur, will potentially meet the cost and efficiency requirements for terawatt photovoltaics. The scientific tasks of the project include: 1) First-principles studies of iron oxysulfide and copper oxysulfide as solar photovoltaic materials; 2) Development of deposition and sulfurization methods for sulfurized hematite; 3) Investigation of its electrical and optical properties as a function of sulfur content; and 4) Development of solution-based n-type and p-type doping methods for hematite. The major innovations in this project include: 1) the use of three Earth-abundant elements, iron, oxygen and sulfur, for bandgap engineering to create a semiconductor better suited for solar photovoltaics; 2) the use of largely solution-based processes for film deposition and doping to ensure low-cost solar cells in the end; and 3) a multidisciplinary approach, where first-principles studies and experimental studies are joined to push forward the technology.Non-technical Description: The success of this project will enable a sustainable solar cell technology, which is capable of low-cost, high-efficiency and most importantly terawatt-scale deployment, allowing solar electricity to become a major source of energy in our future. In addition, this project includes a targeted effort to increase the representation of American Indians in science and engineering as well as increase the awareness of local Arizona tribes on photovoltaic technologies. The principal investigators work with entities such as the American Indian Science and Engineering Society and Arizona Department of Commerce to promote photovoltaic technologies in remote tribal communities, provide research opportunities to American Indian science and engineering students, and engage and interest American Indian youth about science and engineering in general. This project also provides synergistic support to the newly-established U.S. Photovoltaic Manufacturing Consortium (PVMC) for its mission to facilitate a robust domestic solar cell industry. The success of this project will provide a technology pipeline for PVMC, while PVMC provides industrial connections for this project.

技术描述：该项目的目标是合成和研究硫氧化铁，特别是硫化赤铁矿，其目标是取代当前太阳能电池技术中的关键组件，用于下一代光伏发电。具有适当硫浓度的硫化赤铁矿将有可能满足太瓦光伏发电的成本和效率要求。该项目的科学任务包括：1）氧硫化铁和氧硫化铜作为太阳能光伏材料的第一性原理研究； 2）硫化赤铁矿沉积和硫化方法的开发； 3) 研究其电学和光学特性与硫含量的关系； 4) 开发基于溶液的赤铁矿n型和p型掺杂方法。该项目的主要创新包括：1）利用铁、氧和硫这三种地球丰富的元素进行带隙工程，以制造更适合太阳能光伏发电的半导体； 2）采用主要基于溶液的薄膜沉积和掺杂工艺，以确保最终太阳能电池的低成本； 3）多学科方法，将第一性原理研究和实验研究相结合来推动该技术的发展。非技术描述：该项目的成功将实现可持续的太阳能电池技术，该技术能够低成本、高效率-效率，最重要的是太瓦级部署，使太阳能成为我们未来的主要能源。此外，该项目还包括一项有针对性的努力，以提高美洲印第安人在科学和工程领域的代表性，并提高亚利桑那州当地部落对光伏技术的认识。主要研究人员与美洲印第安人科学与工程学会和亚利桑那州商务部等实体合作，在偏远部落社区推广光伏技术，为美洲印第安人科学与工程专业的学生提供研究机会，并吸引美洲印第安人年轻人对科学和技术的兴趣。工程一般。该项目还为新成立的美国光伏制造联盟（PVMC）提供协同支持，以实现其促进国内太阳能电池行业强劲发展的使命。该项目的成功将为PVMC提供技术管道，而PVMC则为本项目提供产业对接。