RUI: Collaborative Proposal: Visible and Near-Infrared Electronic Spectroscopy of Metal-Containing Diatomic Radicals from Intracavity Laser Absorption Techniques

RUI：合作提案：利用腔内激光吸收技术对含金属双原子自由基进行可见光和近红外电子光谱分析

• 批准号: 0213363
• 负责人: Leah O'Brien
• 金额: --
• 依托单位: Southern Illinois University at Edwardsville
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-08-01 至 2007-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0213363&HistoricalAwards=false
• 关键词: RUI; Collaborative; Proposal; Visible; Near

In this collaborative research project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, O'Brien will conduct research on the electronic spectroscopy of metal containing diatomic radicals CuO, NiH, NiCl, and NiF. The goal of the work is to provide new or improved molecular constants for a series of electronic states and to construct the energy level scheme and potential curves of these species. These species are characterized by their open shell structure, which give rise to a host of interactions between nuclear, electronic, vibrational, and rotational degrees of freedom. Besides being of intrinsic interest, the results of this research will also have bearing on other fields such as astrophysics. Experimental techniques are based on intracavity laser absorption spectroscopy, the equipment for which is located at the University of Missouri at Saint Louis. This research will be conducted with undergraduate and MS level graduate students who will receive knowledge and training in the techniques of contemporary experimental and theoretical spectroscopy.This project consists of a collaboration between researchers at a primarily undergraduate institution and a major research university. The research program is designed to provide new information about the energies of a set of metal containing diatomic molecules, the results of which will be useful to other fields such as astrophysics. The project provides training in research to undergraduate and intermediate level graduate students in advanced contemporary techniques of laser spectroscopy. The project also contains an outreach program that will allow gifted high school students to participate in the research.

在这个由化学部实验物理化学计划资助的合作研究项目中，奥布莱恩将对含有硅藻的金属的电子光谱进行研究，这些金属含有硅藻激素，NIH，NIH，NIH和NIF。 这项工作的目的是为一系列电子状态提供新的或改进的分子常数，并构建这些物种的能级方案和潜在曲线。 这些物种的特征是它们的开放壳结构，这会导致核，电子，振动和旋转自由度之间的许多相互作用。 除了具有内在兴趣之外，这项研究的结果还将与其他领域（例如天体物理学）有关系。 实验技术基于腔内激光吸收光谱，该光谱谱图位于密苏里大学圣路易斯大学。 这项研究将与本科和MS级别的研究生进行，他们将接受当代实验和理论光谱技术的知识和培训。该项目由主要研究生机构与一所主要研究大学的研究人员之间的合作组成。 该研究计划旨在提供有关一组含有双原子分子的金属能量的新信息，其结果将对其他领域（例如天体物理学）有用。 该项目为研究生和中级研究生提供了研究培训。 该项目还包含一个外展计划，该计划将允许有才华的高中生参加研究。